Solvent- and additive-free oxidative amidation of aldehydes using a recyclable oxoammonium salt

被引：15
|
作者：
Sandoval, Arturo Leon [1 ]
Doherty, Katrina E. [1 ]
Wadey, Geoffrey P. [1 ]
Leadbeater, Nicholas E. [1 ]
机构：
[1] Univ Connecticut, Dept Chem, 55 North Eagleville Rd, Storrs, CT 06269 USA
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2022年 / 20卷 / 11期
关键词：
EFFICIENT AEROBIC OXIDATION; VISIBLE-LIGHT PHOTOREDOX; CATALYTIC-SYSTEM; ALCOHOLS; AMIDES; AMINES; TEMPO; TRANSFORMATIONS; TRANSAMIDATION; TERTIARY;
D O I：
10.1039/d2ob00307d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A range of acyl azoles have been prepared from aromatic, heteroaromatic, and aliphatic aldehydes by means of an oxidative amidation reaction. The methodology employs a substoichiometric quantity of an oxoammonium salt as the oxidant. It avoids the need for additives such as a base, is run solvent-free, and the oxoammonium salt is recyclable.
引用
收藏
页码：2249 / 2254
页数：6
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