Efficient One-Pot Synthesis of Unsymmetrical Gold(I) N-Heterocyclic Carbene Complexes and Their Use as Catalysts

被引：59
|
作者：
Hashmi, A. Stephen K. [1 ]
Yu, Yang [1 ]
Rominger, Frank [1 ]
机构：
[1] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany
来源：
ORGANOMETALLICS | 2012年 / 31卷 / 03期
关键词：
KITPHOS MONOPHOSPHINES; TEMPLATE SYNTHESIS; PHENOL SYNTHESIS; PALLADIUM; PLATINUM; LIGANDS; CYCLOISOMERIZATION; ACCESS; AMIDES;
D O I：
10.1021/om2008919
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Eleven different gold(I) complexes of new NHC ligands were prepared in excellent yield, demonstrating the versatility of the new route to NHC complexes. While the influence of electronically different ligands on the synthesis of the catalysts was small, the catalytic activities of the products differed significantly.
引用
收藏
页码：895 / 904
页数：10
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