Comparison study of two aldehyde group finishing agents in surface modification of up-conversion luminescence materials

被引:2
|
作者
Cui Lili [1 ]
Fan Huili [1 ]
Xiao Junping [1 ]
Xu Xiaowei [2 ]
机构
[1] Univ Sci & Technol Beijing, Dept Chem, Beijing 100083, Peoples R China
[2] Univ Sci & Technol Beijing, Dept Inorgan Nonmet Mat, Beijing 100083, Peoples R China
基金
中国国家自然科学基金;
关键词
luminescence materials; up-conversion; surface modification; luminescence; aldehyde groups;
D O I
10.1016/S1001-0521(08)60100-X
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Surface modification of up-conversion luminescence materials (Na[Y0.57Yb0.39Er0.04]F-4 modified by amino groups) by grafting and modifying with aldehyde groups was studied by means of Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), then nogravimetric analysis (TGA), and emission spectrum (EM). The surface modification effect was compared using two different finishing agents, p-phthalaldehyde and glutaraldehyde. It was found that the surface of up-conversion luminescence materials could be modified by aldehyde groups of the two finishing agents, the systematic dispersibility and the thermostability of the up-conversion luminescence material modified by p-phthalaldehyde were better than those of the material modified by glutaraldehyde, and the luminous intensity of the material modified by p-phthalaldehyde was increased. The AI (the ratio of the suspended segmental quality in the specimen to the total mass of the specimen) of the material modified by p-phthalaidehyde was higher than that of the material modified by glutaraldehyde. It is obviously seen that the embellishment effect of p-phthalaldehyde as a finishing agent was better than that of glutaraldehyde. In addition, the reasons why p-phthalaldehyde is a good finishing agent are also explained.
引用
收藏
页码:127 / 130
页数:4
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