New routes to organodecaborane polymers via ruthenium-catalyzed ring-opening metathesis polymerization

被引：30
|
作者：
Wei, XL [1 ]
Carroll, PJ [1 ]
Sneddon, LG [1 ]
机构：
[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA
来源：
ORGANOMETALLICS | 2004年 / 23卷 / 02期
关键词：
D O I：
10.1021/om0342107
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compounds 6-(norbornenyl)decaborane and 6-(cyclooctenyl)decaborane were synthesized in >95% yields by the titanium-catalyzed reaction of norbornadiene and cyclooctadiene with decaborane. Ring-opening metathesis polymerization of these monomers employing either first- or second-generation Grubbs catalysts produced the corresponding poly(6-(norbornenyl)decaborane) and poly(6-(cyclooctenyl)decaborane) polymers with M-n > 30 kDa and polydispersities between 1.1 and 1.8.
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页码：163 / 165
页数：3
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