Conjugated microporous poly (aryleneethynylene) networks

被引：1292
|
作者：
Jiang, Jia-Xing
Su, Fabing
Trewin, Abbie
Wood, Colin D.
Campbell, Nell L.
Niu, Hongjun
Dickinson, Calum
Ganin, Alexey Y.
Rosseinsky, Matthew J.
Khimyak, Yaroslav Z.
Cooper, Andrew I.
机构：
[1] Univ Liverpool, Dept Chem, Liverpool, Merseyside, England
[2] Univ Liverpool, Ctr Mat Discovery, Liverpool L69 3BX, Merseyside, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 45期
关键词：
conjugation; microporous materials; networks; polymerization;
D O I：
10.1002/anie.200701595
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Rigid wiry nets: Conjugated microporous polymer networks are formed by Sonogashira-Hagihara coupling. Although these materials are amorphous, the micropore size and surface area can be controlled by varying the length of the phenyleneethynylene struts (see picture; the network is shown in blue, and one 1,3,5-substituted benzene node and three connected struts are highlighted with C gray and H white). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：8574 / 8578
页数：5
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