Boosting the Nucleophilicity of Phosphole Lone Pairs by Isomerization

被引：13
|
作者：
Ciric, Ana [1 ]
Mathey, Francois [1 ]
机构：
[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 21期
关键词：
ARYL CHLORIDES; COMPLEXES;
D O I：
10.1021/om100423r
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The phosphole isomer 4c can be obtained by nickelocene reduction complexation from the corresponding sulfide. It displays a ligating ability comparable to that of tristert-butylphosphine, and its [LPdCl2](2) complex efficiently catalyzes the deboronation homocoupling of arylboronic acids.
引用
收藏
页码：4785 / 4786
页数：2
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