Epitaxial strontium oxide layers on silicon for gate-first and gate-last TiN/HfO2 gate stack scaling

被引:3
|
作者
Frank, Martin M. [1 ]
Marchiori, Chiara [2 ]
Bruley, John [1 ]
Fompeyrine, Jean [2 ]
Narayanan, Vijay [1 ]
机构
[1] IBM Corp, Thomas J Watson Res Ctr, Yorktown Hts, NY 10598 USA
[2] IBM Res Zurich, CH-8803 Ruschlikon, Switzerland
关键词
MOSFET; Gate dielectrics; Metal gate electrodes; Replacement gate; Molecular beam epitaxy; Surface passivation;
D O I
10.1016/j.mee.2011.03.070
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
We show that a thin epitaxial strontium oxide (SrO) interfacial layer enables scaling of titanium nitride/hafnium oxide high-permittivity (high-k) gate stacks for field-effect transistors on silicon. In a low-temperature gate-last process, SrO passivates Si against SiO2 formation and silicidation and equivalent oxide thickness (EOT) of 5 angstrom is achieved, with competitive leakage current and interface trap density. In a gate-first process, Sr triggers HfO2-SiO2 intermixing, forming interfacial high-k silicate containing both Sr and Hf. Combined with oxygen control techniques, we demonstrate an EOT of 6 angstrom with further scaling potential. In both cases, Sr incorporation results in an effective workfunction that is suitable for n-channel transistors. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:1312 / 1316
页数:5
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