The determination of mercury in silver by laser-excited atomic fluorescence spectrometry with electrothermal atomization

被引：4
|
作者：
Baker, CL
Smith, BW
Bolshov, MA
Winefordner, JD
机构：
[1] University of Florida, Gainesvilie, FL, 32611-7200
[2] Visiting from Inst. of Spectroscopy, RAS, 142092, Troizk, Moscow Region
来源：
SPECTROSCOPY LETTERS | 1996年 / 29卷 / 08期
关键词：
mercury; silver; atomic fluorescence spectroscopy; laser excitation; electrothermal atomization;
D O I：
10.1080/00387019608007140
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
This work shows that laser excited atomic fluorescence spectrometry, LEAFS, combined with electrothermal atomization, ETA, is useful for the determination of trace concentrations of mercury in small amounts of silver metal. Only minimal sample preparation procedures, such as dilution of very concentrated solutions and digestion of solid samples, are necessary. The practical limit of detection for this work is found to be blank limited, 50 pg/ml, and the instrumental limit of detection was laser scatter limited at 7 pg/ml.
引用
收藏
页码：1497 / 1512
页数：16
相关论文
共 50 条
12345