No marked kinetic isotope effect in the peroxone (H2O2/D2O2+O3) reaction:: Mechanistic consequences

被引：54
|
作者：
Sein, Myint Myint
Golloch, Alfred
Schmidt, Torsten C.
von Sonntag, Clemens
机构：
[1] Max Planck Inst Bioanorgan Chem, D-45413 Mulheim, Germany
[2] Leibniz Inst Oberflachenmodifizierung, D-04303 Leipzig, Germany
[3] Univ Duisburg Essen, Instrumentalle Analyt Chem, D-47057 Duisburg, Germany
来源：
CHEMPHYSCHEM | 2007年 / 8卷 / 14期
关键词：
kinetics; ozone; peroxides; radicals; reactive; intermediates;
D O I：
10.1002/cphc.200700493
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
(Graph Presented) Radical species: Controversy surrounds the peroxone reaction mechanism; does the rate-determining step involve an electron-transfer or a hydride-transfer reaction? The authors re-investigate the peroxone reaction in D2O to resolve the issue (see figure). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2065 / 2067
页数：3
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