Tandem [2+1] cycloaddition-ring expansion of bicyclic Alkenes with tertiary propargylic acetates catalyzed by palladium(II)-Coordinated phosphinous acid

被引：34
|
作者：
Bigeault, Julie [1 ]
de Riggi, Innocenzo [1 ]
Gimbert, Yves [2 ]
Giordano, Laurent [1 ]
Buono, Gerard [1 ]
机构：
[1] Univ Aix Marseille, ECM, Inst Sci Mol Marseille ISM2, F-13397 Marseille 20, France
[2] Univ Grenoble 1, CNRS, UMR 5250, Dept Chim Mol,ICMG FR 2607, F-38041 Grenoble, France
来源：
SYNLETT | 2008年 / 07期
关键词：
palladium; secondary phosphine oxides; tertiary propargylic acetate; bicyclic alkene; tandem reaction;
D O I：
10.1055/s-2008-1042919
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium-SPO complex catalyzed the tandem [2+1] cycloaddition-ring expansion of norbornene derivatives with tertiary propargylic acetates to afford bicyclo[3.2.1]octadienes.
引用
收藏
页码：1071 / 1075
页数：5
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