Role of water in the chemisorption of PCl3 and POCl3 on pyrogenic silica

被引：2
|
作者：
Bogatyryov, VM [1 ]
机构：
[1] NAS Ukraine, Inst Surface Chem, UA-252022 Kiev, Ukraine
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1999年 / 66卷 / 01期
关键词：
silica; surface; phosphorus;
D O I：
10.1007/BF02475758
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The interaction of gaseous PCl3 and POCl3 with dried and wetted pyrogenic silica has been studied by IR spectroscopy. The acceleration of the chemisorption accompanied by the formation of Si-O-P bonds in the presence of water vapor has been observed only with phosphorus trichloride.
引用
收藏
页码：177 / 181
页数：5
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