Two new tercopolymers incorporating electron-rich benzodithiophene and electron-accepting pyrrolo[3,4-c]pyrrole-1,3-dione and difluorobenzothiadiazole derivatives for polymer solar cells

被引：3
|
作者：
Tamilavan, Vellaiappillai [1 ,2 ]
Kim, Seungmin [2 ]
Agneeswari, Rajalingam [1 ]
Lee, Dal Yong [2 ]
Cho, Shinuk [3 ]
Jeong, Junghyun [2 ]
Jin, Youngeup [4 ]
Park, Sung Heum [2 ]
Hyun, Myung Ho [1 ]
机构：
[1] Pusan Natl Univ, Chem Inst Funct Mat, Dept Chem, Busan 690735, South Korea
[2] Pukyong Natl Univ, Dept Phys, Busan 608737, South Korea
[3] Univ Ulsan, Dept Phys, Ulsan 680749, South Korea
[4] Pukyong Natl Univ, Dept Ind Chem, Busan 608739, South Korea
来源：
POLYMER BULLETIN | 2018年 / 75卷 / 01期
基金：
新加坡国家研究基金会;
关键词：
Polymer solar cells; Tercopolymers; Benzodithiophene-based polymers; Pyrrolo[3,4-c]pyrrole-1,3-dione-based polymers; Benzothiadiazole-based polymers; POWER CONVERSION EFFICIENCY; BAND-GAP POLYMERS; HIGH-PERFORMANCE; PHOTOVOLTAIC PROPERTIES; COPOLYMERS; TERPOLYMERS; SINGLE; IMIDE; UNITS; SELENOPHENE;
D O I：
10.1007/s00289-017-2028-9
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two new tercopolymers (RP1 and RP2) containing electron-donating benzodithiophene, weak electron-accepting pyrrolo[3,4-c]pyrrole-1,3-dione derivative and strong electron-accepting 5,6-difluorobenzothiadiazole derivative were prepared. The opto-electrical studies showed that RP1 and RP2 displayed identical optical band gaps (E (g) similar to 1.72 eV) and highest occupied/lowest unoccupied molecular orbital energy levels (HOMO/LUMO similar to -5.32 eV/-3.60 eV). The polymer solar cells prepared with the configuration of ITO/PEDOT:PSS/RP1:PC70BM (1:1.5 wt%) + 3 vol% DIO/Al and ITO/PEDOT:PSS/RP2:PC70BM (1:1.5 wt%) + 3 vol% DIO/Al exhibited a maximum power conversion efficiency (PCE) of 5.16% (V (oc) similar to 0.76 V, J (sc) similar to 10.93 mA/cm(2), and FF similar to 0.62) and a PCE of 3.56% (V (oc) similar to 0.67 V, J (sc) similar to 9.67 mA/cm(2), and FF similar to 0.55), respectively.
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收藏
页码：239 / 253
页数：15
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  • [1] Two new tercopolymers incorporating electron-rich benzodithiophene and electron-accepting pyrrolo[3,4-c]pyrrole-1,3-dione and difluorobenzothiadiazole derivatives for polymer solar cells
    Vellaiappillai Tamilavan
    Seungmin Kim
    Rajalingam Agneeswari
    Dal Yong Lee
    Shinuk Cho
    Junghyun Jeong
    Youngeup Jin
    Sung Heum Park
    Myung Ho Hyun
    [J]. Polymer Bulletin, 2018, 75 : 239 - 253
  • [2] Effects of the incorporation of bithiophene instead of thiophene between the pyrrolo[3,4-c]pyrrole-1,3-dione units of a bis(pyrrolo[3,4-c]pyrrole-1,3-dione)-based polymer for polymer solar cells
    Tamilavan, Vellaiappillai
    Kim, Seungmin
    Sung, Ji Yeong
    Lee, Dal Yong
    Cho, Shinuk
    Jin, Youngeup
    Jeong, Junghyun
    Park, Sung Heum
    Hyun, Myung Ho
    [J]. NEW JOURNAL OF CHEMISTRY, 2016, 40 (12) : 10153 - 10160
  • [3] Preparation of a New Polymer Containing Benzodithiophene and Imide-functionalized Pyrrolo[3,4-c]pyrrole-1,3-dione Units for Polymer Solar Cells
    Agneeswari, Rajalingam
    Roh, Kyung Hwan
    Tamilavan, Vellaiappillai
    Jin, Youngeup
    Park, Sung Heum
    Hyun, Myung Ho
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2015, 36 (02): : 636 - 642
  • [4] Photocurrent enhancement of an efficient large band gap polymer incorporating benzodithiophene and weak electron accepting pyrrolo[3,4-c]pyrrole-1,3-dione derivatives via the insertion of a strong electron accepting thieno[3,4-b]thiophene unit
    Tamilavan, Vellaiappillai
    Lee, Jihoon
    Agneeswari, Rajalingam
    Lee, Dal Yong
    Cho, Shinuk
    Jin, Youngeup
    Park, Sung Heum
    Hyun, Myung Ho
    [J]. POLYMER, 2015, 80 : 95 - 103
  • [5] Effects of the incorporation of an additional pyrrolo[3,4-c]pyrrole-1,3-dione unit on the repeating unit of highly efficient large band gap polymers containing benzodithiophene and pyrrolo[3,4-c]pyrrole-1,3-dione derivatives
    Agneeswari, Rajalingam
    Shin, Insoo
    Tamilavan, Vellaiappillai
    Lee, Dal Yong
    Cho, Shinuk
    Jin, Youngeup
    Park, Sung Heum
    Hyun, Myung Ho
    [J]. ORGANIC ELECTRONICS, 2016, 30 : 253 - 264
  • [6] Pyrrolo[3,4-c]pyrrole-1,3-dione Based Wide Band Gap Polymers for Polymer Solar Cells
    Tamilavan, Vellaiappillai
    Kim, Heewon
    Kim, Seungmin
    Cho, Shinuk
    Jin, Youngeup
    Jeong, Junghyun
    Park, Sung Heum
    Hyun, Myung Ho
    [J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2017, 17 (08) : 5556 - 5561
  • [7] Benzodithiophene-based polymers containing novel electron accepting selenophene-incorporated pyrrolo[3,4-c]pyrrole-1,3-dione units for highly efficient thin film transistors and polymer solar cells
    Tamilavan, Vellaiappillai
    Park, Jong Baek
    Kang, In-Nam
    Hwang, Do-Hoon
    Hyun, Myung Ho
    [J]. SYNTHETIC METALS, 2014, 198 : 230 - 238
  • [8] Enhanced photovoltaic performances of bis(pyrrolo[3,4-c]pyrrole-1,3-dione)-based wide band gap polymer via the incorporation of an appropriate spacer unit between pyrrolo[3,4-c]pyrrole-1,3-dione units
    Tamilavan, Vellaiappillai
    Kim, Seungmin
    Sung, Jiyeong
    Lee, Dal Yong
    Cho, Shinuk
    Jin, Youngeup
    Jeong, Junghyun
    Park, Sung Heum
    Hyun, Myung Ho
    [J]. ORGANIC ELECTRONICS, 2017, 42 : 34 - 41
  • [9] Benzodithiophene based ternary copolymer containing covalently bonded pyrrolo[3,4-c]pyrrole-1,3-dione and benzothiadiazole for efficient polymer solar cells utilizing high energy sunlight
    Tamilavan, Vellaiappillai
    Kim, Seungmin
    Agneeswari, Rajalingam
    Lee, Dal Yong
    Cho, Shinuk
    Jin, Youngeup
    Jeong, Junghyun
    Park, Sung Heum
    Hyun, Myung Ho
    [J]. ORGANIC ELECTRONICS, 2016, 38 : 283 - 291
  • [10] IN VITRO EVALUATION OF ANTITUBULIN ACTIVITY OF TETRAHYDROPYRROLO[3,4-c]PYRROLE-1,3-DIONE DERIVATIVES
    Zelazkova, Jana
    [J]. REVUE ROUMAINE DE CHIMIE, 2019, 64 (06) : 493 - 495
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