CO, CO2 and CS2 activation by divalent ytterbium hydrido complexes

被引：5
|
作者：
Shi, Xianghui [1 ]
Rajeshkumar, Thayalan [2 ,3 ]
Maron, Laurent [2 ,3 ]
Cheng, Jianhua [1 ,4 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, 5625 Renmin St, Changchun 130022, Peoples R China
[2] Univ Toulouse, CNRS, LPCNO, 135 Ave Rangueil, F-31077 Toulouse, France
[3] Univ Toulouse, UPS, INSA, 135 Ave Rangueil, F-31077 Toulouse, France
[4] Univ Sci & Technol China Hefei, Hefei 230026, Anhui, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 09期
基金：
中国国家自然科学基金;
关键词：
CARBON-MONOXIDE; SELECTIVE FORMATION; EARTH; CHEMISTRY; DIOXIDE; ALKYL; BOND; HYDROGENATION; REACTIVITY; LN;
D O I：
10.1039/d1cc06449e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Treatment of a divalent ytterbium hydride complex [(Tp(Ad,iPr))-Yb(H)(THF)] (Tp(Ad,iPr) = hydrotris(3-adamantyl-5-isopropyl-pyrazolyl)borate) (1) with CO, CO2 and CS2 resulted in the formation of a divalent ytterbium ethenediolate complex [(Tp(Ad,iPr))Yb](2)(cis-OCH=CHO) (2), a formate complex [(Tp(Ad,iPr))Yb(kappa(2)-O2CH)(THF)] (3), and a trivalent ytterbium ethenetetrathiolate complex [(Tp(Ad,iPr))-Yb-III](2)(C2S4) (4), respectively. DFT calculations were carried out to elucidate the reaction profiles of complexes 3 and 4.
引用
收藏
页码：1362 / 1365
页数：4
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