FABRICATION OF BIPHASE BiVO4 PARTICLES WITH ENHANCED PHOTOCATALYTIC PERFORMANCE VIA A SURFACTANT-FREE HYDROTHERMAL ROUTE

被引:1
|
作者
Qian, Hongzhi [1 ]
Lai, Min [1 ,2 ,3 ]
Huang, Xiaogu [1 ]
Wang, Wei [1 ]
Xu, Chaoqi [1 ]
Yong, Haibo [1 ]
Wen, Yan [1 ]
Zhou, Yingjie [1 ]
机构
[1] Nanjing Univ Informat Sci & Technol, Sch Phys & Optoelect Engn, Nanjing 210044, Jiangsu, Peoples R China
[2] Collaborat Innovat Ctr Atmospher Environm & Equip, Nanjing 210044, Jiangsu, Peoples R China
[3] Jiangsu Res Ctr Ocean Survey Technol, Nanjing 210044, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Biphase; BiVO4; heterostructures; photocatalytic performance; VISIBLE-LIGHT IRRADIATION; DEGRADATION; NANOPARTICLES;
D O I
10.1142/S0218625X16500323
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Biphase bismuth vanadate (BiVO4) particles have been synthesized using a surfactant-free hydrothermal strategy. Biphase BiVO4 were formed at pH = 3, 5 and 7 with a bandgap between 2.28 eV and 2.86 eV, which are those of monoclinic and tetragonal phases, respectively. Photocatalytic tests on the degradation of rhodamine B (RhB) under visible-light irradiation showed that biphase BiVO4 with both monoclinic and tetragonal structures synthesized at pH = 3 achieved enhanced photocatalytic performance in comparison with pure monoclinic and tetragonal phases, which was attributed to the heterostructures leading to low recombination rate of electron-hole pairs.
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页数:5
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