Removal of Atenolol and Isoproturon in Aqueous Solutions by Adsorption in a Fixed-Bed Column

被引:51
|
作者
Luis Sotelo, Jose [1 ]
Ovejero, Gabriel [1 ]
Rodriguez, Araceli [1 ]
Alvarez, Silvia [1 ]
Garcia, Juan [1 ]
机构
[1] Univ Complutense Madrid, Fac Ciencias Quim, Dept Ingn Quim, Grp Catalisis & Proc Separac CyPS, E-28040 Madrid, Spain
关键词
ACTIVATED CARBON; BREAKTHROUGH CURVES; METHYLENE-BLUE; WASTE-WATER; PACKED-BED; PREDICTION; PHARMACEUTICALS; ENVIRONMENT; EXCHANGE; PHENOL;
D O I
10.1021/ie300334q
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this work, the removal of a beta-blocker, atenolol, and a pesticide, isoproturon, from aqueous solutions by adsorption on granular activated carbon fixed-bed columns has been studied. The effect of important operation parameters on breakthrough curves as column length (Z = 1.0-3.0 cm), initial concentration of atenolol or isoproturon (C-0 = 50.0-500.0 mu g.L-1),and volumetric flow rate (Q = 1.5 mL.min(-1)) was studied. Breakthrough time of the bed was found to increase with an increase in the value of the column length, and with a decrease in the value of initial concentration or flow rate. Mathematical models, as Bohart-Adams, Thomas, Yoon-Nelson, and Clark were applied to the experimental data for the prediction of the breakthrough curves, and to determine the characteristic parameters of the bed.
引用
收藏
页码:5045 / 5055
页数:11
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