Thermodynamic and statistical analysis of soybean oil extraction process using renewable solvent

被引：37

作者：

Rodrigues, Christianne E. C. ^{[1
]}

Aracava, Keila K. ^{[1
]}

Abreu, Fernanda N. ^{[1
]}

机构：

[1] Univ Sao Paulo, Dept Food Engn ZEA FZEA, Separat Engn Lab LES, BR-13635900 Pirassununga, SP, Brazil

来源：

INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY | 2010年 / 45卷 / 11期

基金：

巴西圣保罗研究基金会;

关键词：

Enthalpy change; entropy change; ethanol; free energy change; response surface methodology; solid-liquid equilibrium; solvent extraction; RICE BRAN OIL; ALTERNATIVE SOLVENTS; ETHANOL; KINETICS; HEXANE; SYSTEM;

D O I：

10.1111/j.1365-2621.2010.02417.x

中图分类号：

TS2 [食品工业];

学科分类号：

0832 ;

摘要：

The main goal of this work was to evaluate thermodynamic parameters of the soybean oil extraction process using ethanol as solvent. The experimental treatments were as follows: aqueous solvents with water contents varying from 0 to 13% (mass basis) and extraction temperature varying from 50 to 100 degrees C. The distribution coefficients of oil at equilibrium have been used to calculate enthalpy, entropy and free energy changes. The results indicate that oil extraction process with ethanol is feasible and spontaneous, mainly under higher temperature. Also, the influence of water level in the solvent and temperature were analysed using the response surface methodology (RSM). It can be noted that the extraction yield was highly affected by both independent variables. A joint analysis of thermodynamic and RSM indicates the optimal level of solvent hydration and temperature to perform the extraction process.

引用

页码：2407 / 2414

页数：8

共 50 条

[1] A NEW SOLVENT EXTRACTION PROCESS FOR SOYBEAN OIL
SWEENEY, OR
ARNOLD, LK
[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1949, 26 (12) : 697 - 700
[2] Thermodynamic analysis of solvent extraction of oil in a packed bed
Majumdar, GC
Sengupta, SP
[J]. TRANSACTIONS OF THE ASAE, 1997, 40 (04): : 1141 - 1149
[3] Soybean oil extraction using ethyl acetate and 1-butanol: From solvent selection to thermodynamic assessment
Gasparetto, Henrique
Nunes, Ana Luiza Barrachini
de Castilhos, Fernanda
Salau, Nina Paula Goncalves
[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2022, 113 : 450 - 460
[4] OPTIMIZATION OF OIL EXTRACTION FROM SOYBEAN USING AZEOTROPIC TERNARY SOLVENT MIXTURES AND CAKE ANALYSIS
Aremu, Mujidat O.
Usenu, Aonughe I.
Salam, Kazeem K.
Bolarinwa, Islamiyat F.
Araromi, Dauda O.
Alade, Abass O.
[J]. CARPATHIAN JOURNAL OF FOOD SCIENCE AND TECHNOLOGY, 2023, 15 (04) : 154 - 167
[5] SOLVENT EFFECTS ON THE PRODUCTS OF SOYBEAN OIL EXTRACTION
BECKEL, AC
BELTER, PA
SMITH, AK
[J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1948, 25 (01) : 7 - 9
[6] Pressurized liquid extraction of soybean oil using intermittent process with ethanol and hexane as solvent: Extraction yield and physicochemical parameters comparison
Ramos, Paulo Rodolfo
Vicentini-Polette, Carolina Medeiros
Mazalli, Monica Roberta
de Lima Caneppele, Fernando
de Oliveira, Alessandra Lopes
[J]. JOURNAL OF FOOD PROCESS ENGINEERING, 2024, 47 (02)
[7] Kinetics of soybean oil extraction using ethanol as solvent: Experimental data and modeling
Toda, Tatiane Akemi
Sawada, Mirian Megumi
Rodrigues, Christianne E. C.
[J]. FOOD AND BIOPRODUCTS PROCESSING, 2016, 98 : 1 - 10
[8] Enzymatic hydrolysis of soybean for solvent and mechanical oil extraction
Bargale, PC
Sosulski, K
Sosulski, FW
[J]. JOURNAL OF FOOD PROCESS ENGINEERING, 2000, 23 (04) : 321 - 327
[9] Dependence of Oil Extraction Factor on Thermodynamic Parameters of Solvent
M. N. Dadashev
D. G. Filenko
N. M. Bulaeva
V. A. Vinokurov
R. R. Mursalov
[J]. Chemistry and Technology of Fuels and Oils, 2016, 52 : 409 - 413
[10] Dependence of Oil Extraction Factor on Thermodynamic Parameters of Solvent
Dadashev, M. N.
Filenko, D. G.
Bulaeva, N. M.
Vinokurov, V. A.
Mursalov, R. R.
[J]. CHEMISTRY AND TECHNOLOGY OF FUELS AND OILS, 2016, 52 (04) : 409 - 413

← 1 2 3 4 5 →