Generation effects on the microstructure and product distribution in ethylene polymerization promoted by dendritic nickel catalysts

被引：48
|
作者：
Benito, JM [1 ]
de Jesús, E [1 ]
de la Mata, FJ [1 ]
Flores, JC [1 ]
Gómez, R [1 ]
机构：
[1] Univ Alcala De Henares, Dept Quim Inorgan, E-28871 Alcala De Henares, Spain
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 41期
关键词：
D O I：
10.1039/b511379m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Carbosilane dendrimers Gn-[(ONNMe2)NiBr2] m, containing up to sixteen terminal pyridylimine nickel complexes, have been studied as catalysts for polymerization of ethylene; the microstructure and the oligomer/polymer distribution are significantly affected by the generation of the dendritic precursor.
引用
收藏
页码：5217 / 5219
页数：3
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