Comment on "First-order phase transitions: Equivalence between bimodalities and the Yang-Lee theorem"

被引:6
|
作者
Touchette, H [1 ]
机构
[1] Univ London, Sch Math Sci, London E1 4NS, England
基金
加拿大自然科学与工程研究理事会;
关键词
phase transitions; Yang-Lee theorem; nonconcave entropy;
D O I
10.1016/j.physa.2005.05.098
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
I discuss the validity of a result put forward recently by Chomaz and Gulminelli [Physica A 330 (2003) 451] concerning the equivalence of two definitions of first-order phase transitions. T show that distributions of zeros of the partition function fulfilling the conditions of the Yang-Lee Theorem are not necessarily associated with nonconcave microcanonical entropy functions or, equivalently, with canonical distributions of the mean energy having a bimodal shape, as claimed by Chomaz and Gulminelli. In fact, such distributions of zeros can also be associated with concave entropy functions and unimodal canonical distributions having affine parts. A simple example is worked out in detail to illustrate this subtlety. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:375 / 379
页数:5
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