A novel 3D network constructed from tetra-substituted trisalkoxy-hexavanadate clusters: Na2[V6IVO7{(OCH2)3CNH2}4]

被引：8

作者：

Xie, Youquan ^{[1
]}

Huang, Bo ^{[1
]}

Xu, Chao ^{[1
]}

Hu, Xunliang ^{[1
]}

Chen, Weizhou ^{[1
]}

Xiao, Zicheng ^{[1
]}

Wu, Pingfan ^{[1
]}

机构：

[1] Hubei Univ Technol, Hubei Prov Key Lab Green Mat Light Ind, Inst POM Based Mat, Wuhan 430068, Hubei, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2017年 / 84卷

基金：

中国国家自然科学基金;

关键词：

Polyoxovanadate; Hydrothermal synthesis; Crystal structure; 3D framework; Cyclic voltammetry; POLYOXOMETALATE; POLYOXOVANADATES; FRAMEWORKS; CATALYSTS; SERIES;

D O I：

10.1016/j.inoche.2017.08.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new tetra-substituted trisalkoxy-hexavanadate Na-2[(V6O7)-O-IV{(OCH2)(3)CCH2NH2}(4)] (1) has been synthesized under hydrothermo conditions and structurally characterized by IR, TG, UV-Vis, elemental analysis and single crystal X-ray diffraction. Compound 1 exhibit a 3D network similar to the silica oxide in which each POM cluster was connected to four neighboring clusters by sodium ions, results in good thermostability. The electrochemical property of 1 was also studied by cyclic voltammetry. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：96 / 98

页数：3

共 18 条

[1] Facile synthesis of an organically-derivatized hexavanadate containing the remote amino group, TBA2[V6O13{(OCH2)3CNH2}2]
Bayaguud, Aruuhan
Chen, Kun
Wei, Yongge
CRYSTENGCOMM, 2016, 18 (22): : 4042 - 4045
[2] Coordination compounds of polyoxovanadates with a hexametalate core. Chemical and structural characterization of [V6VO13{(OCH2)3CR}2]2$MI N, [V6VO11(OH)2{(OCH2)3CR}2 ], [V4IVV2VO9(OH)4{(OCH2)3C R$LFB C2 ]2-, and [V6IVO7(OH)6{(OCH2)3CR}2 ] 2-
Chen, Qin
Gosborn, David P.
Scholes, Charles P.
Tan, Xiao-Ling
Zubieta, Jon
Journal of the American Chemical Society, 1992, 114 (12)
[3] HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF HEXAVANADIUM POLYOXO ALKOXIDE ANION CLUSTERS - CRYSTAL-STRUCTURES OF THE VANADIUM(IV) SPECIES BA[V6O7(OH)3((OCH2)3CCH3)3].3H2O AND NA2[V6O7((OCH2)3CCH2CH3)4], OF THE MIXED-VALENCE COMPLEX (ME3NH)[VIV5VVO7(OH)3((OCH2)3CCH3)3], AND OF THE FLUORO DERIVATIVE NA[V6O6F(OH)3((OCH2)3CCH3)3].3H2O
KHAN, MI
CHEN, Q
HOPE, H
PARKIN, S
OCONNOR, CJ
ZUBIETA, J
INORGANIC CHEMISTRY, 1993, 32 (13) : 2929 - 2937
[4] A NOVEL HEXAVANADATE CORE - SYNTHESIS AND STRUCTURE OF THE MIXED-VALENCE CLUSTER [V6O8((OCH2)3CET)2((OCH2)2C(CH2OH)(ET))4]2- AND A COMPARISON WITH THE HEXAMETALLATE CORE OF [V6O13(OME)3((OCH2)3CCH2OH)]2-
QIN, C
ZUBIETA, J
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (15) : 1180 - 1182
[5] CIS-/TRANS-ISOMERISM OF BIS-(TRISALKOXY)-HEXAVANADATES - CIS-NA-2[V-6(IV)O-7(OH)(6)((OCH2)(3)CCH2OH)(2))-CENTER-DOT-8H(2)O, CIS-(CN3H6)3[V-5(IV)O-V(13)((OCH2)(3)CCH2OH)(2)]-CENTER-DOT-4,5H(2)O AND TRANS-(CN3H6)(2)[V-6(V)O-13((OCH2)(3)CCH2OH)(2)]-CENTER-DOT-H2O
MULLER, A
MEYER, J
BOGGE, H
STAMMLER, A
BOTAR, A
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (11): : 1818 - 1831
[6] A Novel (3,6,6)-Connected 3D Supramolecular Framework Constructed from 2D (4,4) Coordination Network [Pb(H2pimdc)2(H2O)2]n
Wang, Ni
Li, Dong-Sheng
Zhao, Jun
Zhang, Peng
He, Qiu-Fen
Ke, Xi-Jun
Li, Cai
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (10) : 762 - 767
[7] A Novel 3D Supramolecular Network Constructed from [Cu（4,4'-bipyridine）(O2CMe)2]2 Molecular Ladders by Hydrogen Bonding
YANG Ea② WANG Xiao-Qinb QIN Ye-Yanb a (College of Chemistry & Materials Science
结构化学, 2006, (11) : 1365 - 1368
[8] A novel 3D supramolecular network constructed from [Cu(4,4-bipyridine)(O2CMe)2]2 molecular ladders by hydrogen Bonding
Yang Ea
Wang Xiao-Qin
Qin Ye-Yan
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (11) : 1365 - 1368
[9] HEXAVANADIUM POLYOXO ALKOXIDE ANION CLUSTERS - STRUCTURES OF THE MIXED-VALENCE SPECIES (ME3NH)[V(IV)5V(V)O7(OH)3(CH3C(CH2O)3)3] AND OF THE REDUCED COMPLEX NA2[V(IV)6O7(CH3CH2C(CH2O)3)4]
KHAN, MI
CHEN, Q
ZUBIETA, J
GOSHORN, DP
INORGANIC CHEMISTRY, 1992, 31 (09) : 1556 - 1558
[10] A novel chiral 3D architecture containing left-handed helical chains constructed from vanadate clusters:: [Zn(bpp)V2O6] (bpp=1,3-di-4-pyridylpropane)
Qu, Xiaoshu
Xu, Lin
Li, Fengyan
Gao, Guanggang
INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (12) : 1404 - 1408

← 1 2 →