High resolution electrical characterisation of Ag-conducting heterogeneous chalcogenide glasses

被引：15
|
作者：
Piarristeguy, A. A. [1 ]
Ramonda, M. [2 ]
Frolet, N. [1 ]
Ribes, M. [1 ]
Pradel, A. [1 ]
机构：
[1] Univ Montpellier 2, Inst Charles Gerhardt Montpellier, Equipe Physicochim Mat Desordonnes & Poreux PMDP, CC1503, F-34095 Montpellier 5, France
[2] Univ Montpellier 2, LMCP, F-34095 Montpellier, France
来源：
SOLID STATE IONICS | 2010年 / 181卷 / 25-26期
关键词：
Ag chalcogenide glasses; Phase separation; Near field microscopy; Conductivity; ATOMIC-FORCE MICROSCOPY; PHASE-SEPARATION; IONIC-CONDUCTIVITY; NANOSCALE; CARBON;
D O I：
10.1016/j.ssi.2010.06.050
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Electric force microscopy (EFM) and conductive atomic force microcopy (C-AFM) are introduced to perform nanoscale electrical characterization of phase separated Ag(x)(Ge(0.25)Se(0.75))(100-x) glasses. Changes in the relative permittivity are found for both phases when the silver content is changed. Furthermore, the sensitivity of the C-AFM technique revealed current variations of a few pico-amperes in the Ag-rich phase for the different glass compositions. This result confirms that the increase in conductivity of the Ag-Ge-Se samples in the region of high ionic conduction (x > 8-10 at.%) arises from an increase in conductivity of the Ag-rich phase and not from an increase in amount of Ag-rich phase with a fixed composition and conductivity. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：1205 / 1208
页数：4
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    [J]. NANOSTRUCTURED MATERIALS FOR ADVANCED TECHNOLOGICAL APPLICATIONS, 2009, : 435 - 444
  • [2] Local electrical characterization of Ag conducting chalcogenide glasses using electric force microscopy
    Piarristeguy, A. A.
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    Pradel, A.
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2010, 356 (44-49) : 2402 - 2405
  • [3] Topological Study of Phase-Separated Ag-Conducting Chalcogenide Glasses Using Peak Force Quantitative Nano-Mechanical Characterization
    Piarristeguy, Andrea A.
    Le Parc, Rozenn
    Ramonda, Michel
    Escalier, Raphael
    Pradel, Annie
    [J]. FRONTIERS IN MATERIALS, 2020, 6
  • [4] Local vibrational and mechanical characterization of Ag conducting chalcogenide glasses
    Piarristeguy, A.
    Le Parc, R.
    Ramonda, M.
    Escalier, R.
    Grillo, I.
    Cuello, G. J.
    Cristiglio, V.
    Pradel, A.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 762 : 906 - 914
  • [5] STRUCTURE OF FAST-ION CONDUCTING CHALCOGENIDE GLASSES - THE AG-AS-SE SYSTEM
    BENMORE, CJ
    SALMON, PS
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1993, 156 : 720 - 724
  • [6] Radiation induced functionality of chalcogenide glasses probed by high resolution XPS
    Shpotyuk, O.
    Golovchak, R.
    Jain, H.
    Kovalskiy, A.
    [J]. PHYSICS AND CHEMISTRY OF GLASSES-EUROPEAN JOURNAL OF GLASS SCIENCE AND TECHNOLOGY PART B, 2008, 49 (06): : 314 - 316
  • [7] Study of electrical and microstructural properties of Ag-doped As-S-Se chalcogenide glasses
    Cajko, Kristina O.
    Sekulic, Dalibor L.
    Petrovic, Dragoslav M.
    Labas, Vladimir
    Minarik, Stanislav
    Rakic, Srdjan J.
    Lukic-Petrovic, Svetlana R.
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2021, 571
  • [8] High resolution electrical characterisation of organic photovoltaic blends
    Douheret, O.
    Swinnen, A.
    Breselge, M.
    Van Severen, I.
    Lutsen, L.
    Vanderzande, D.
    Manca, J.
    [J]. MICROELECTRONIC ENGINEERING, 2007, 84 (03) : 431 - 436
  • [9] PREPARATION AND ELECTRICAL-CONDUCTIVITY OF SOME CHALCOGENIDE GLASSES AT HIGH-TEMPERATURES
    BAKER, EH
    WEBB, LM
    [J]. JOURNAL OF MATERIALS SCIENCE, 1974, 9 (07) : 1128 - 1132
  • [10] High-resolution XPS for determining the chemical order in chalcogenide network glasses
    Golovchak, R.
    Shpotyuk, O.
    Kovalskiy, A.
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS-X, 2023, 18
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