The first example of the catalytic activity of (μ-H)Os3(μ-OCNR1R2)(CO)10 clusters in the double bond migration reactions of allylic systems functionalised with an amido group

被引：0

作者：

Ershova, VA ^{[1
]}

Tkachev, SV ^{[1
]}

Golovin, AV ^{[1
]}

Al't, LY ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

MENDELEEV COMMUNICATIONS | 1998年 / 06期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As exemplified by the isomerisation of N-allylacetamide in the presence of hydridocarbonyl complexes (mu-H)Os-3(mu-(OCNRR2)-R-1)(CO)(10) (R-1 = H, Alk; R-2 = Alk), it has been demonstrated for the first time that they are effective catalysts for the [1,2]-double bond shift under mild conditions in allylic compounds functionalised with an amido group.

引用

页码：208 / 210

页数：3

共 15 条

[1] Reactions of triosmium clusters with indole: X-ray structures of [Os3(CO)10(μ-OH)(μ-OMeCO)] and [Os3(μ-H)(CO)10(μ-1, 2-η2-NC8H6)]
Noorjahan Begum
Md. Iqbal Hyder
G. M. Golzar Hossain
Shariff E. Kabir
Shafali R. Karmakar
Journal of Chemical Crystallography, 2005, 35 : 799 - 807
[2] Reactions of triosmium clusters with indole:: X-ray structures of [Os3(CO)10(μ-OH)(μ-OMeCO)] and [Os3(μ-H)(CO)10(μ-1, 2-η2-NC8H6)]
Begum, N
Hyder, MI
Hossain, GMG
Kabir, SE
Karmakar, SR
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2005, 35 (10) : 799 - 807
[3] Study of allylic rearrangement in (μ-H) Os3(μ-O=CNRCH2CH=CH2)(CO)10 (R = H or CH3) clusters
Maksakov, VA
Kirin, VP
Tkachev, SV
Golovin, AV
RUSSIAN CHEMICAL BULLETIN, 1999, 48 (11) : 2158 - 2161
[4] Study of allylic rearrangement in (μ-H)Os3(μ-O=CNRCH2CH=CH2)(CO)10 (R=H or CH3) clusters
V. A. Maksakov
V. P. Kirin
S. V. Tkachev
A. V. Golovin
Russian Chemical Bulletin, 1999, 48 : 2158 - 2161
[5] Molecular rearrangements of diynes coordinated to triosmium carbonyl clusters:: reactions of [Os3(μ-H)2(CO)10] and [Os3(CO)10(MeCN)2] with 1,4-dipyridylbuta-1,3-diyne
Clarke, LP
Cole, JM
Davies, JE
French, A
Koentjoro, OF
Raithby, PR
Shields, GP
NEW JOURNAL OF CHEMISTRY, 2005, 29 (01) : 145 - 153
[6] Reactions of unsaturated quinoline triosmium clusters [Os3(CO)9(μ3-η2-C9H5(4-R)N)(μ-H)] (R = Me or H) with tetramethylthiourea:: X-ray structures of [Os3(CO)8(μ-η2-C9H5(4-Me)N) (η2-SC(NMe2NCH2Me)(μ-H)2] and [Os3(CO)9 (μ-η2-C9H6N)(η1-SC(NMe2)2)(μ-H)]
Begum, N
Bennett, DW
Hossain, GMG
Kabir, SE
Sharmin, A
Haworth, DT
Siddiquee, TA
Rosenberg, E
JOURNAL OF CLUSTER SCIENCE, 2005, 16 (03) : 413 - 428
[7] Reactions of Unsaturated Quinoline Triosmium Clusters [Os3(CO)9(μ3-η2-C9H5(4-R)N)(μ-H)] (R=Me or H) with Tetramethylthiourea: X-ray Structures of [Os3(CO)8(μ-η2-C9H5(4-Me)N)(η2-SC(NMe2NCH2Me)(μ-H)2] and [Os3(CO)9(μ-η2-C9H6N)(η1-SC(NMe2)2)(μ-H)]
Noorjahan Begum
Dennis W. Bennett
G. M. Golzar Hossain
Shariff E. Kabir
Ayesha Sharmin
Daniel T. Haworth
Tasneem A. Siddiquee
Edward Rosenberg
Journal of Cluster Science, 2005, 16 : 413 - 428
[8] THE REACTIONS OF [HOS3(CO)11]- WITH MAIN GROUP HALIDE SPECIES - A ROUTE TO TERMINAL AND BRIDGED MIXED METAL-CLUSTERS - CRYSTAL-STRUCTURE OF [(MU-H)OS3(CO)10(MU-SBPH2)]
JOHNSON, BFG
LEWIS, J
WHITTON, AJ
BOTT, SG
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 389 (01) : 129 - 138
[9] α-Diimine Ligand Coordination and C–H Bond Activation in the Reaction of Os3(CO)10(MeCN)2 with 6-R-2,2′-Bipyridine (where R = Et, Ph): X-ray Diffraction Structures of the Ortho-Metalated Hydride Clusters HOs3(CO)9(N2C10H6-6-R)
Carl J. Carrano
Xiaoping Wang
Bhaskar Poola
Cynthia B. Powell
Michael G. Richmond
Journal of Chemical Crystallography, 2009, 39 : 820 - 826
[10] Complexation and C-H bond activation of 2,2′:6′,2"-terpyridyl molecules on triosmium carbonyl clusters: Synthesis and characterization of the double-cluster {Cp3Fe4(CO)4(C5H4-terpyridyl)Os3(μ-H)(CO)n} (n=9, 10)
Yu, Yi-Jing
Yeh, Wen-Yann
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (23) : 3681 - 3686

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