Mechanism and kinetic properties for OH-initiated atmospheric degradation of the organophosphorus pesticide diazinon

Diazinon is a member of the organophosphorus class of insecticides. It has been regarded as an important atmospheric pollutant because of its high detection-frequency in the air and potential adverse effects on humans and wildlife. In this paper, the reaction mechanism and possible degradation products for the OH-initiated atmospheric degradation of diazinon were investigated and the rate constants of crucial elementary steps over the temperature range of 180-370 K were predicted. Present results show that OH addition to C4 atom in the pyrimidyl ring, H abstraction from the CH moiety as well as OH addition to P atom are the dominant pathways for the reaction of diazinon with OH radicals. The dominant degradation products are diazoxon, SO(2), P3, CH(3)CHO, P4, CH(3)CO, P14 as well as CH(3)CHCH(3). This work provides a comprehensive investigation of the OH-initiated atmospheric degradation of diazinon and should help to clarify its potential risk to non-targets. (C) 2011 Published by Elsevier Ltd.