Effect of solvent on reaction rate constant of reaction between carbon dioxide and glycidyl methacrylate using Aliquat 336 as a catalyst

被引：0
|
作者：
Park, Sang-Wook [1 ]
Lee, Jae-Wook [2 ]
机构：
[1] Pusan Natl Univ, Div Chem Engn, Pusan 609735, South Korea
[2] Sogang Univ, Dept Chem Engn, Seoul 121742, South Korea
来源：
NEW DEVELOPMENT AND APPLICATION IN CHEMICAL REACTION ENGINEERING, 4TH ASIA-PACIFIC CHEMICAL REACTION ENGINEERING SYMPOSIUM (APCRE 05) | 2006年 / 159卷
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D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Absorption rates of carbon dioxide were measured in organic solutions of glycidyl methacrylate at 101.3 kPa to obtain the reaction kinetics between carbon dioxide and glycidyl methacrylate using tricaprylylmethylammonium chloride(Aliquat 336) as catalysts. The reaction rate constants were estimated by the mass transfer mechanism accompanied by the pseudo-first-order fast reaction. An empirical correlation between the reaction rate constants and the solubility parameters of solvents, such as toluene, N-methyl-2-pirrolidinone, and dimethyl sulfoxide was presented.
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页码：345 / 348
页数：4
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