Ethyl biodiesel production from non-edible oils of Balanites aegyptiaca, Azadirachta indica, and Jatropha curcas seeds - Laboratory scale development

被引:23
|
作者
Nitiema-Yefanova, Svitlana [1 ]
Coniglio, Lucie [2 ]
Schneider, Raphael [2 ]
Nebie, Roger H. C. [3 ]
Bonzi-Coulibaly, Yvonne L. [1 ]
机构
[1] Univ Ouagadougou, Dept Chim, Lab Chim Organ Struct & React, 03 BP 7021, Ouagadougou 03, Burkina Faso
[2] Univ Lorraine, Ecole Natl Super Ind Chim Nancy, Lab React & Genie Proc, UMR CNRS 7274, 1 Rue Grandville BP 20451, F-54001 Nancy, France
[3] Ctr Natl Rech Sci & Technol, Dept Subst Nat, Inst Rech Sci Appl & Technol, 03 BP 7047, Ouagadougou 03, Burkina Faso
关键词
Ethyl biodiesel; Non-edible vegetable oils; Two-stage procedure; Single homogeneous catalyst; Intermediate glycerol addition; WASTE COOKING OIL; OF-THE-ART; VEGETABLE-OILS; NEEM OIL; CATALYZED TRANSESTERIFICATION; HETEROGENEOUS CATALYSTS; PROCESS OPTIMIZATION; SOYBEAN OIL; CANOLA OIL; FUEL;
D O I
10.1016/j.renene.2016.04.100
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
By starting first at the laboratory scale, optimal operating conditions for the reaction unit aimed at producing ethyl biodiesels from non-edible vegetable oils (NEVO) were determined with the ultimate objective of proposing an on-farm processing technology that should be sustainable for emerging countries. Three NEVO widely available in Burkina Faso were selected: Balanites aegyptiaca (BA), Azadirachta indica (AI), and Jatropha curcas (JC) oils. Their conversion to fatty acid ethyl esters (FAEE) was conducted via a two-stage procedure under atmospheric pressure: an alkali-catalyzed ethanolysis at ambient temperature for the BA and AI oils (leading to 93 and 87 wt.% FAEE respectively) and an acid-catalyzed ethanolysis at the normal boiling of the alcohol for the JC oil (leading to 89 wt.% FAEE). Based on the intermediate addition of glycerol at ambient temperature, the two-stage procedure combines chemical kinetics, chemical equilibrium, and phase equilibrium phenomena. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:881 / 890
页数:10
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