Structural characterization of shielded isomeric europlum complexes with metal-metal contact

被引：57
|
作者：
Law, Ga-Lal
Wong, Ka-Leung
Yang, Yang-Yi
Yi, Qiao-Yuan
Jia, Guohua
Wong, Wing-Tak
Tanner, Peter A.
机构：
[1] City Univ Hong Kong, Dept Biol & Chem, Kowloon, Hong Kong, Peoples R China
[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[3] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 23期
关键词：
D O I：
10.1021/ic701162j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New luminescent isomeric europium(III) complexes with carboxylic carbonyl group coordination (I and II) have been prepared by solvothermal synthesis using the ligand 2,2 '-bipyridine-4,4 '-dicarboxylic acid (bpdc), with the nonradiatively shielded Eu3+ coordination sphere completed by dimethyl sulfoxide ligands. The room temperature IR spectra and Eu3+ luminescence spectra do not provide a definitive distinction between I and II, but low-temperature luminescence can give a clear identification.
引用
收藏
页码：9754 / 9759
页数：6
相关论文
共 50 条
  • [1] Synthesis and characterization of homometallic cobalt complexes with metal-metal interactions
    Xin, Xiaoqing
    Sheng, Weiming
    Zhang, Qian
    Qi, Ruogu
    Zhu, Qin
    Zhu, Congqing
    [J]. DALTON TRANSACTIONS, 2024, 53 (37) : 15696 - 15702
  • [2] METAL-METAL BONDS IN TRANSITION METAL COMPLEXES
    LEWIS, J
    NYHOLM, RS
    [J]. SCIENCE PROGRESS, 1964, 52 (208) : 557 - &
  • [3] Characterization and applications of metal-metal interactions in early/late heterobimetallic complexes
    Thomas, Christine M.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [4] SYNTHESIS AND CHARACTERIZATION OF MODEL METAL-METAL COMPLEXES OF DIACETYLENES .2.
    AGHATABAY, N
    BAYAT, C
    [J]. TURKISH JOURNAL OF CHEMISTRY, 1995, 19 (02): : 142 - 145
  • [5] PHOTOCHEMISTRY OF METAL-METAL BONDED COMPLEXES
    WRIGHTON, MS
    GRAFF, JL
    LUONG, JC
    REICHEL, CL
    ROBBINS, JL
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 180 (AUG): : 56 - INOR
  • [6] Spectral and structural characterization of amidate-bridged platinum-thallium complexes with strong metal-metal bonds
    Chen, Wanzhi
    Liu, Fenghui
    Matsumoto, Kazuko
    Autschbach, Jochen
    Le Guennic, Boris
    Ziegler, Tom
    Maliarik, Mikhail
    Glaser, Julius
    [J]. INORGANIC CHEMISTRY, 2006, 45 (11) : 4526 - 4536
  • [7] RESISTANCE MEASUREMENT IN METAL-METAL CONTACT EXPERIMENTS
    PASHLEY, MD
    PETHICA, JB
    [J]. JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1981, 14 (05): : 584 - 586
  • [8] Structural divergence of heavy metal complexes with isomeric thiophenecarboxylates
    Lang, Alex
    Villa, Eric
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [9] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF METAL-METAL ATOM MULTIPLY BONDED (MO, W) COMPLEXES SUPPORTED BY SELENOLATE LIGANDS
    CHISHOLM, MH
    PARKIN, IP
    HUFFMAN, JC
    STREIB, WE
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 200 : 393 - INOR
  • [10] Metal-metal multiply-bonded complexes of technetium .3. Preparation and characterization of phosphine complexes of technetium possessing a metal-metal bond order of 3.5
    Cotton, FA
    Haefner, SC
    Sattelberger, AP
    [J]. INORGANIC CHEMISTRY, 1996, 35 (07) : 1831 - 1838
12345