Interactions of proline in non-aqueous anionic, cationic and nonionic surfactants at different temperatures

被引:3
|
作者
Anwar, Ali [1 ]
Shahjahan [1 ]
机构
[1] Jamia Millia Islamia, Dept Chem, New Delhi 110025, India
关键词
partial molar volume; viscosity coefficient; interaction;
D O I
10.1016/S1872-1508(08)60044-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Density and viscosity data of proline (Pro) in sodium dodecyl sulfate/cetyltrimethylammonium bromide/ poly (oxyethylene) isooctyl phenyl ether in formamide were measured at 298.15, 303.1.5, 308.15, and 313.15 K and 0.1 MPa. The density data were utilized to evaluate standard partial molar volumes (phi(0)(v)) and partial molar isobaric expansibility (phi(0)(E) ). The viscosity data were used to evaluate A- and B-coefficients, free energy of activation of viscous flow (Delta mu(1)0*) and (Delta mu(2)0*), per mole of solvent and solute respectively, enthalpy (Delta H*) and entropy (Delta S*) of activation of viscous flow. The results obtained were utilized in the qualitative elucidation of the Pro-surfactant/formamide and Pro-Pro interactions in the present systems.
引用
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页码:987 / 991
页数:5
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