Lanthanoid-containing Ni-based catalysts for dry reforming of methane: A review

被引:47
|
作者
Salaev, M. A. [1 ]
Liotta, L. F. [2 ]
Vodyankina, O. V. [1 ]
机构
[1] Tomsk State Univ, 36 Lenin Ave, Tomsk 634050, Russia
[2] Italian Natl Res Council CNR, Inst Study Nanostruct Mat ISMN, Via Ugo La Malfa 153, I-90146 Palermo, Italy
基金
俄罗斯科学基金会;
关键词
DRM; Lanthanoid-containing Ni catalyst; Cerium oxide; La2O3; Metal-support interaction; SUPPORTED NICKEL-CATALYSTS; LOW COKE FORMATION; OXIDE FUEL-CELL; CARBON-DIOXIDE; SYNGAS PRODUCTION; NI/SBA-15; CATALYSTS; HYDROGEN-PRODUCTION; NANOCOMPOSITE CATALYSTS; PARTIAL SUBSTITUTION; STRUCTURED REACTORS;
D O I
10.1016/j.ijhydene.2021.11.086
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dry reforming of methane (DRM) is known to produce synthesis gas through the utilization of greenhouse gases to ensure environmentally benign process and rational use of natural resources. Many catalyst formulations operating at "ideal" conditions were proposed for DRM reaction, including those based on noble (Pt, Rh) and non-noble (Ni, Co) metals supported on various oxides. This review is focused on the recent advances in lanthanoid-containing Ni-based DRM catalysts. We consider the performance of Ni-based catalysts supported on LnO(x) oxides (La2O3, CeO2, etc.), promotion of the said composites by noble or transition metals, organization of pristine and promoted Ni-LnO(x) interfaces on the surfaces of various supports, including ordered materials. Analysis of features of the high-performance DRM catalysts is provided. The outlook of the existing challenges and opportunities in the rational design of a new generation of lanthanoid-containing Ni-based catalysts for dry reforming of methane and other hydrocarbons is provided. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:4489 / 4535
页数:47
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