A study of electrochemical process of Fe(CN)63-/Fe(CN)64- on gold electrode by electrochemical quartz crystal impedance system

被引：0

作者：

Xie, QJ ^{[1
]}

Wang, J ^{[1
]}

Xu, ZN ^{[1
]}

Liu, HW ^{[1
]}

Zhang, YY ^{[1
]}

Yao, SZ ^{[1
]}

机构：

[1] Hunan Normal Univ, Chem Res Inst, Changsha 410081, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 1999年 / 20卷 / 04期

关键词：

in situ dynamic quartz crystal impedance analysis; electrochemistry; ferricyanide; ferrocyanide;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Admittance spectra of quartz crystal resonance were measured in situ in the electrochemical process of Fe(CN)(6)(3-)/Fe(CN)(6)(4-) on Au electrode in 1.0 mol/L Na2SO4 aqueous solution using an electrochemical quartz crystal impedance system, Changes in motional resistance R-1 were well reversible with potential, but resonant frequency f(o) series resonant frequency f(s) and parallel resonant frequency f(p) had significant rising drifts besides somewhat reversible changes with potential. It is concluded that changes in R-1 were caused by variations in solution density and viscosity near electrode surface, but frequency responses resulted from both changes of solution properties and corrosion of Au electrode in anodic process.

引用

页码：549 / 551

页数：3

共 4 条

[1] Dynamic quartz crystal impedance measurements of polyvinylferrocene film deposition
Bandey, HL
Gonsalves, M
Hillman, AR
Glidle, A
Bruckenstein, S
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 410 (02): : 219 - 227
[2] KANAZAWA KK, 1985, ANAL CHIM ACTA, V175, P99
[3] COMPUTATION OF EQUIVALENT-CIRCUIT PARAMETERS OF QUARTZ CRYSTALS IN CONTACT WITH LIQUIDS AND STUDY OF LIQUID PROPERTIES
MURAMATSU, H
TAMIYA, E
KARUBE, I
[J]. ANALYTICAL CHEMISTRY, 1988, 60 (19) : 2142 - 2146
[4] HIGH-FREQUENCY IMPEDANCE ANALYSIS OF QUARTZ-CRYSTAL MICROBALANCES .1. GENERAL-CONSIDERATIONS
NOEL, MAM
TOPART, PA
[J]. ANALYTICAL CHEMISTRY, 1994, 66 (04) : 484 - 491

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