Crystal structures capture multiple stoichiometric states of an aqueous self-assembling oligourea foldamer

被引：7

作者：

Collie, Gavin W. ^{[1
]}

Lombardo, Caterina M. ^{[2
]}

Yoo, Sung Hyun ^{[2
]}

Pulka-Ziach, Karolina ^{[3
]}

Gabelica, Valerie ^{[4
]}

Mackereth, Cameron D. ^{[4
]}

Rosu, Frederic ^{[5
]}

Guichard, Gilles ^{[2
]}

机构：

[1] AstraZeneca, Discovery Sci, R&D, Cambridge, England

[2] Univ Bordeaux, CNRS, Inst Europeen Chim & Biol, Bordeaux INP,CBMN,UMR 5248, 2 Rue Robert Escarpit, F-33607 Pessac, France

[3] Univ Warsaw, Fac Chem, Pasteura 1, PL-02093 Warsaw, Poland

[4] Univ Bordeaux, CNRS, INSERM, U1212,ARNA,UMR 5320,IECB, F-33600 Bordeaux, France

[5] Univ Bordeaux, CNRS, INSERM, IECB,UMS 3033, F-33600 Pessac, France

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 75期

关键词：

DOUBLE HELICES; SEQUENCE;

D O I：

10.1039/d1cc03604a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report here an oligourea foldamer able to self-assemble in aqueous conditions into helix bundles of multiple stoichiometries. Importantly, we report crystal structures of several of these stoichiometries, providing a series of high-resolution snap-shots of the structural polymorphism of this foldamer and uncovering a novel self-assembly.

引用

页码：9514 / 9517

页数：5

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