Zeolite-catalyzed acetalization reaction of furfural with alcohol under solvent-free conditions

被引：16
|
作者：
Song, Heyuan [1 ]
Jin, Fuxiang [2 ]
Liu, Qiao [2 ]
Liu, Hailong [2 ]
机构：
[1] Lanzhou Jiaotong Univ, Sch Chem & Chem Engn, Lanzhou 730070, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
来源：
MOLECULAR CATALYSIS | 2021年 / 513卷
关键词：
Furfural; Zeolite; Furfural acetals; Acetalization; Free solvents; ACID; ALDEHYDES; EFFICIENT; BIODIESEL; HYDROGENATION; SAPO-34; BIOMASS; ROUTES;
D O I：
10.1016/j.mcat.2021.111752
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Acetalization reactions present a viable method for producing valuable chemicals and protecting carbonyl functionalities in organic compounds. Herein, several commercial zeolites were used as solid acid catalysts in the acetalization of biomass-derived furfural with alcohols under solvent-free conditions. The effects of major reaction parameters such as catalyst concentration, reaction temperature, and reaction time were investigated. Among the tested catalysts, SAPO-34 with appropriate acid sites and textural structure exhibited the highest catalytic activity under optimized reaction conditions. Additionally, the catalyst showed excellent recyclability and no obvious deactivation was observed even after using it six times.
引用
收藏
页数：7
相关论文
共 50 条
  • [1] Acetalization of Carbonyl Compounds Catalyzed by Bismuth Triflate Under Solvent-Free Conditions
    Aliyan, Hamid
    Fazaeli, Razieh
    Massah, Ahmad Reza
    Momeni, Ahmad Reza
    Naghash, Hamid Javaherian
    Moeinifard, Behzad
    [J]. ASIAN JOURNAL OF CHEMISTRY, 2010, 22 (02) : 873 - 876
  • [2] Zeolite-catalyzed synthesis of substituted benzimidazoles under solvent-free condition and microwave irradiation
    Mobinikhaledi, A.
    Zendehdel, M.
    Jamshidi, F. Hasanvand
    [J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2007, 37 (03) : 175 - 177
  • [3] Ruthenium-catalyzed solvent-free conversion of furfural to furfuryl alcohol
    Tukacs, Jozsef M.
    Bohus, Marton
    Dibo, Gabor
    Mika, Laszlo T.
    [J]. RSC ADVANCES, 2017, 7 (06): : 3331 - 3335
  • [4] Ionic liquids catalyzed Biginelli reaction under solvent-free conditions
    Peng, JJ
    Deng, YQ
    [J]. TETRAHEDRON LETTERS, 2001, 42 (34) : 5917 - 5919
  • [5] Mannich reaction catalyzed by a novel catalyst under solvent-free conditions
    Yue, Cai Bo
    Yi, Ting Feng
    Zhu, Chuan Bing
    Liu, Gang
    [J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2009, 15 (05) : 653 - 656
  • [6] Highly Efficient Acetalization and Ketalization Catalyzed by Cobaloxime under Solvent-Free Condition
    Zong, Yang
    Yang, Liting
    Tang, Shanyu
    Li, Longjia
    Wang, Wanjie
    Yuan, Bingxin
    Yang, Guanyu
    [J]. CATALYSTS, 2018, 8 (02):
  • [7] Michael addition of indoles to β-nitrostyrenes catalyzed by HY zeolite under solvent-free conditions
    Jeganathan, Mariappan
    Kanagaraj, Kuppusamy
    Dhakshinamoorthy, Amarajothi
    Pitchumani, Kasi
    [J]. TETRAHEDRON LETTERS, 2014, 55 (13) : 2061 - 2064
  • [8] Acetalization of furfural with zeolites under benign reaction conditions
    Rubio-Caballero, Juan Miguel
    Saravanamurugan, Shunmugavel
    Maireles-Torres, Pedro
    Riisager, Anders
    [J]. CATALYSIS TODAY, 2014, 234 : 233 - 236
  • [9] The Suzuki reaction under solvent-free conditions
    Nielsen, SF
    Peters, D
    Axelsson, O
    [J]. SYNTHETIC COMMUNICATIONS, 2000, 30 (19) : 3501 - 3509
  • [10] TMEDA Catalyzed Henry (Nitroaldol) Reaction under Metal and Solvent-free Conditions
    Majhi, Anjoy
    Kadam, Santosh T.
    Kim, Sung Soo
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2009, 30 (08): : 1767 - 1770
12345