Thin liquid/gas diffusion layers for high-efficiency hydrogen production from water splitting

被引:106
|
作者
Mo, Jingke [1 ]
Kang, Zhenye [1 ]
Yang, Gaoqiang [1 ]
Retterer, Scott T. [2 ]
Cullen, David A. [2 ]
Toops, Todd J. [2 ]
Green, Johney B., Jr. [2 ]
Zhang, Feng-Yuan [1 ]
机构
[1] Univ Tennessee, UT Space Inst, Dept Mech Aerosp & Biomed Engn, Nanodynam & High Efficiency Lab Prop & Power Nano, Knoxville, TN 37388 USA
[2] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA
关键词
Proton exchange membrane fuel; cells/electrolyzer cells; Liquid/gas diffusion layers; Hydrogen production; Water splitting; Performance and efficiency; ELECTROLYTE FUEL-CELL; MICROPOROUS LAYER; BIPOLAR PLATES; PERFORMANCE; MEMBRANE; ENERGY; TRANSPORT; OPTIMIZATION; MEDIA; DURABILITY;
D O I
10.1016/j.apenergy.2016.05.154
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this study, a novel titanium thin LGDL with well-tunable pore morphologies was developed by employing nano-manufacturing and was applied in a standard PEMEC. The LGDL tests show significant performance improvements. The operating voltages required at a current density of 2.0 A/cm(2) were as low as 1.69 V, and its efficiency reached a report high of up to 88%. The new thin and flat LGDL with well-tunable straight pores has been demonstrated to remarkably reduce the ohmic, interfacial and transport losses. In addition, well-tunable features, including pore size, pore shape, pore distribution, and thus porosity and permeability, will be very valuable for developing PEMEC models and for validation of its simulations with optimal and repeatable performance. The LGDL thickness reduction from greater than 350 mu m of conventional LGDLs to 25 mu m will greatly decrease the weight and volume of PEMEC stacks, and represents a new direction for future developments of low-cost PEMECs with high performance. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:817 / 822
页数:6
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