Viscoelastic properties at the sol-gel transition

被引:0
|
作者
Del Gado, E
de Arcangelis, L
Coniglio, A
机构
[1] Univ Naples Federico II, Dipartimento Sci Fis, INFM, I-80131 Naples, Italy
[2] Univ Naples 2, Dipartimento Ingn Informat, I-81031 Aversa, CE, Italy
关键词
D O I
10.1002/1521-3900(200106)171:1<79::AID-MASY79>3.0.CO;2-U
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We present a study of molecular dynamics at the sol-gel transition. Application of percolation and bond-fluctuation dynamics provides critical exponents for viscoelastic properties in a strong covalent gel and shows a complex non-exponential relaxation behaviour. The results are in good agreement with experimental findings and offer interesting pointers for discussions.
引用
收藏
页码:79 / 85
页数:7
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