Properties of C-doped CrTiN films on the 316L stainless steel bipolar plate for PEMFC

被引:34
|
作者
Mi, Baosen [1 ]
Chen, Zhuo [1 ,2 ]
Wang, Quan [1 ]
Li, Yifeifei [1 ]
Qin, Ziwei [1 ,2 ]
Wang, Hongbin [1 ,2 ,3 ]
机构
[1] Shanghai Univ, Sch Mat Sci & Engn, Shanghai, Peoples R China
[2] Panxing Technol Zhejiang Co LTD, Hangzhou, Zhejiang, Peoples R China
[3] Shanghai Engn Res Ctr Met Parts Green Remanufactu, Shanghai, Peoples R China
关键词
Bipolar plate; Magnetron sputtering; C doped CrTiN film; Corrosion resistance; Interfacial contact resistance; INTERFACIAL CONTACT RESISTANCE; CORROSION BEHAVIOR; ELECTROCHEMICAL PROPERTIES; MECHANICAL-PROPERTIES; FUEL-CELLS; ELECTROLYTE; COATINGS; PERFORMANCE; CRN; TITANIUM;
D O I
10.1016/j.ijhydene.2021.07.109
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
C doped CrTiN films were deposited on 316L stainless steel by magnetron sputtering technology to investigate corrosion resistance and electrical conductivity. The sputtering current of the C target alter to obtain various C contents. The carbon target currents are 0 A, 3 A and 6 A, respectively. The result of SEM confirms that deposited films have a dense and uniform microstructure. CrTiN coating consist of Cr, CrN and TiN phases. With the increase of C carbon target currents, Cr crystal structure vanishes, and the amorphous carbon and carbides appear. The result of the potentiodynamic polarization test in the simulate PEMFC environment reveals that C doped CrTiN coating can improve samples' corrosion resistance. At 1.1 V (vs. SHE) potentiostatic tests, the C-6A has the lowest current density, 6.09 x 10(-7) A/cm(2). Interfacial contact resistance decreases with the addition of C atoms. The C-6A coated sample has the lowest interfacial contact resistance values, 5.5 mU cm(2). (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:32645 / 32654
页数:10
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