Cobalt(III)-Catalyzed Aryl and Alkenyl C-H Aminocarbonylation with Isocyanates and Acyl Azides

被引：168
|
作者：
Li, Jie [1 ]
Ackermann, Lutz [1 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 29期
基金：
欧洲研究理事会;
关键词：
amides; azides; C-H activation; cobalt; isocyanates; CATALYZED DIRECT ARYLATION; CARBON-CARBON BONDS; N-TYPE REACTIONS; ACTIVATION; AMIDATION; ALKYLATION; CYANATION; COMPLEX; ARENES; FUNCTIONALIZATIONS;
D O I：
10.1002/anie.201501926
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Expedient C-H aminocarbonylations of unactivated (hetero)arenes and alkenes were accomplished with a cobalt(III) catalyst that shows high functional group tolerance. The C-H functionalization occurred with excellent chemo-, site-, and diastereoselectivity and enabled step-economical reactions with isocyanates or acyl azides.
引用
收藏
页码：8551 / 8554
页数：4
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