Soil chemical properties and nutrition of conilon coffee fertilized with molybdenum and nitrogen

Molybdenum (Mo) availability is strongly affected by soil pH, which determines the dynamics of electrical charges and the adsorption of molybdate. This study evaluated the effects of nitrogen (N) and Mo application on the chemical properties of a Latossolo Amarelo (Oxisol) and in Coffea canephora nutrition and productivity throughout two productive cycles under field conditions. The experiment was conducted from June 2018 to May 2020. The experimental design used was in randomized blocks, in a 2 x 5 factorial scheme, the first factor being the absence and presence (4 kg ha(-1) yr(-1)) of molybdic fertilization and the second factor was the N dose (300, 500, 700, 900, and 1,100 kg ha(-1) yr(-1)). At the end of each production cycle, soil samples were collected to evaluate the pH(H2O), pH(KCl), exchangeable aluminum, potential acidity, organic matter, and Mo, at layers of 0.00-0.20 and 0.20-0.40 m. Leaves were sampled from the coffee tree to determine Mo and N contents and the coffee beans were harvested to evaluate the yield of processed coffee. The results showed that urea has a high potential for soil acidification, influencing the values of exchangeable aluminum, potential acidity, and Delta pH, at layers of 0.00-0.20 and 0.20-0.40 m. The decrease in pH caused by increasing doses of N increased the density of positive electrical charges of the soil and reduced Mo content in the leaves of C. canephora by 67 %. The application of sodium molybdate via soil was efficient in providing Mo to Conilon coffee and provided a 3.7 % increase in the yield of processed coffee. Nevertheless, molybdic fertilization did not influence the Mo content in the soil in the evaluations carried out at the end of each production cycle.