Integration of hydrothermal carbonization and aqueous phase reforming for energy recovery from sewage sludge

This study investigates the energy recovery from sewage sludge by combining hydrothermal carbonization and aqueous phase reforming of the generated process water. The hydrothermal treatment was carried out at 170 degrees C and 230 degrees C for 1 h, and produced a hydrochar with adequate physicochemical properties, such as a higher heating value (20-24 MJ kg(-1)) than sludge, improved fuel ratio (0.2-0.5) and a broad comprehensive combustion index (5.8 x 10(-7) to 10.0 x 10(-7) min(-2) degrees C-2). Aqueous phase reforming of the process water was carried out at 220 degrees C and 25-29 bar for 4 h. A maximum H-2 yield of 98.7 mmol H-2 gTOC(-1) was achieved using a bimetallic Pt/Rh catalyst supported on carbon black and for the process water obtained at the lowest carbonization temperature. The integration of hydrothermal carbonization and aqueous phase reforming processes is an interesting alternative for the management and energy recovery of sewage sludge, which allows reaching a potential energy recovery of 17.3 MJ per kg of dry sewage sludge, equivalent to 93.5 % gross energy recovery, under optimized conditions.