Catalytic fast pyrolysis of biomass to produce furfural using heterogeneous catalysts

被引:63
|
作者
Chen, Xu [1 ]
Yang, Haiping [1 ]
Chen, Yingquan [1 ]
Chen, Wei [1 ]
Lei, Tingzhou [2 ]
Zhang, Wennan [3 ]
Chen, Hanping [1 ]
机构
[1] Huazhong Univ Sci & Technol, State Key Lab Coal Combust, 1037 Luoyu Rd, Wuhan 430074, Hubei, Peoples R China
[2] Henan Acad Sci, Inst Energy Co Ltd, Zhengzhou 450002, Henan, Peoples R China
[3] Mid Sweden Univ, Dept Chem Engn, SE-85170 Sundsvall, Sweden
基金
中国博士后科学基金;
关键词
Catalytic pyrolysis; Biomass; Furfural; Heterogeneous catalysts; Py-GC/MS; SELECTIVE CONVERSION; ACETIC-ACID; CELLULOSE; CORNCOB; GLUCOSE; XYLOSE; TIO2; HEMICELLULOSE; DECOMPOSITION; HYDROLYSIS;
D O I
10.1016/j.jaap.2017.07.022
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Furfural is a valuable chemical, the production of furfural from renewable biomass resources becomes more attractive in recent years. In this study, biomass fast pyrolysis with heterogeneous catalysts (titanium compounds (TiN, TiO2 and TiOSO4) and metal nitrides (MoN, GaN and VN)) for furfural production was investigated experimentally by means of pyrolysis-gas chromatography/mass-spectrometry (Py-GC/MS). The measurement results indicated that TiN and GaN promoted the furfural compounds production notably mainly through direct decomposition of oligosaccharides. The formation of furfural was promoted when the amount of TiN was increased, and the yield of furfural formed was about 5.5 times the size of that from non-catalytic pyrolysis when TiN/cellulose mass ratio was 4. The furfural yield decreased when the pyrolysis residence time increased from 10 to 30 s, which suggests competitive reactions (formation of 1, 6-anhydro-beta.-D-glucopyranose) against the formation of furfural. TiN, as a catalyst for fast pyrolysis towards furfural production, can be well applied to agriculture biomass residues. Comparing three biomass residues: corncob, wheat straw and cotton stalk, corncob showed higher furfural yield due to the higher holocellulose content, while wheat straw showed higher furfural selectivity.
引用
收藏
页码:292 / 298
页数:7
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