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Interaction of Siberian larch arabinogalactan with amino-containing compounds

被引：8
|
作者：
Mudarisova, R. Kh [1 ]
Badykova, L. A. [1 ]
机构：
[1] Russian Acad Sci, Ufa Res Ctr, Inst Organ Chem, Ufa 450054, Bashkortostan, Russia
来源：
POLYMER SCIENCE SERIES A | 2012年 / 54卷 / 02期
关键词：
POLYSACCHARIDES;
D O I：
10.1134/S0965545X12020083
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The interaction of the natural polysaccharide arabinogalactan and its oxidized fractions with 5-aminosalicylic acid, 4-aminosalicylic acid, and isonicotinic acid hydrazide in aqueous solutions is investigated with the use of physicochemical methods. The compositions and stability constants of the formed complexes are studied, and the optimal conditions of their preparation are found. On the basis of spectral investigations and quantum-chemical calculations, the scheme of interaction between system components that leads to formation of cyclic structures is developed.
引用
收藏
页码：106 / 112
页数：7
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