Magnetic iron oxide nanoparticles as long wavelength photoinitiators for free radical polymerization

被引：27
|
作者：
Dadashi-Silab, Sajjad [1 ]
Yar, Yasemin [2 ]
Acar, Havva Yagci [2 ]
Yagci, Yusuf [1 ,3 ,4 ]
机构：
[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey
[2] Koc Univ, Grad Sch Sci & Engn, TR-34450 Istanbul, Turkey
[3] King Abdulaziz Univ, Fac Sci, CEAMR, Jeddah 21589, Saudi Arabia
[4] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia
来源：
POLYMER CHEMISTRY | 2015年 / 6卷 / 11期
关键词：
SEMICONDUCTOR; PHOTOPOLYMERIZATION; SUNLIGHT; SYSTEMS; ACID; CDS;
D O I：
10.1039/c4py01658k
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Iron oxide nanoparticles (Fe3O4 NPs) capped with lauric acid agents were synthesized and their photocatalytic activity was investigated in free radical photopolymerization of vinyl monomers. These NPs were able to release charge carriers (electron-hole pairs) upon photoexcitation through which the capping agents or an additional amine co-initiator acting as the hole acceptor underwent oxidation to eventually form the initiating radicals. In lauric acid coated Fe3O4 NPs, electron transfer followed by a decarboxylation process accounts for the initiation.
引用
收藏
页码：1918 / 1922
页数：5
相关论文
共 50 条
  • [1] PHOTOINITIATORS FOR FREE-RADICAL POLYMERIZATION
    HAGEMAN, HJ
    PROGRESS IN ORGANIC COATINGS, 1985, 13 (02) : 123 - 150
  • [2] PHOTOINITIATORS FOR FREE-RADICAL POLYMERIZATION
    GRUBER, HF
    PROGRESS IN POLYMER SCIENCE, 1992, 17 (06) : 953 - 1044
  • [3] Multifunctional Magnetic Hydrogels Fabricated by Iron Oxide Nanoparticles Mediated Radical Polymerization
    Ibeaho, Wilson Finold
    Chen, Mingqian
    Shi, Jiasheng
    Chen, Changlong
    Duan, Zhengyu
    Wang, Cui
    Xie, Yunfeng
    Chen, Zhiyong
    ACS APPLIED POLYMER MATERIALS, 2022, 4 (06) : 4373 - 4381
  • [4] Styryl dyes as new photoinitiators for free radical polymerization
    Sokolowska, Jolanta
    Podsiadly, Radoslaw
    Stoczkiewicz, Jakub
    DYES AND PIGMENTS, 2008, 77 (03) : 510 - 514
  • [5] Long-wavelength absorbing photoinitiators based phenothiazine acyldiphenylphosphine oxides for free radical photopolymerization
    Ma, Guanhao
    Luo, Jiangyu
    Qu, Jinqing
    PROGRESS IN ORGANIC COATINGS, 2024, 189
  • [6] Phenacyl Ethyl Carbazolium as a Long Wavelength Photoinitiator for Free Radical Polymerization
    Kara, Merve
    Dadashi-Silab, Sajjad
    Yagci, Yusuf
    MACROMOLECULAR RAPID COMMUNICATIONS, 2015, 36 (23) : 2070 - 2075
  • [7] Morphology effect on zinc oxide quantum photoinitiators for radical polymerization
    Pinkas, Alex
    Waiskopf, Nir
    Gigi, Shira
    Naor, Tom
    Layani, Almog
    Banin, Uri
    NANOSCALE, 2021, 13 (15) : 7152 - 7160
  • [8] TRIARYLSULFONIUM SALTS AS PHOTOINITIATORS OF FREE-RADICAL AND CATIONIC POLYMERIZATION
    CRIVELLO, JV
    LAM, JHW
    JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1979, 17 (12) : 759 - 764
  • [9] Novel dissociative electron transfer photoinitiators for free radical polymerization
    Wrzyszczynski, A
    Paczkowski, J
    POLIMERY, 2004, 49 (09) : 606 - 614
  • [10] Generation of Core/Shell iron oxide magnetic nanoparticles with polystyrene brushes by atom transfer radical polymerization
    Garcia, I.
    Tercjak, A.
    Zafeiropoulos, N. E.
    Stamm, M.
    Mondragon, I.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (20) : 4744 - 4750
12345