2-hydroxyethylammonium formate ionic liquid grafted magnetic nanoparticle as a novel heterogeneous catalyst for the synthesis of substituted imidazoles

被引：30

作者：

Rajabzadeh, Maryam ^{[1
]}

Eshghi, Hossein ^{[1
]}

Khalifeh, Reza ^{[2
]}

Bakavoli, Mehdi ^{[1
]}

机构：

[1] Ferdowsi Univ Mashhad, Dept Chem, Fac Sci, Mashhad 9177948974, Iran

[2] Shiraz Univ Technol, Dept Chem, Shiraz 71555313, Iran

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2018年 / 32卷 / 02期

关键词：

POT EFFICIENT SYNTHESIS; AMMONIUM ACETATE; ALDEHYDES; NANOCATALYST; ALKYLATION; REDUCTION; SOLVENT; BENZIL; SILICA; GREEN;

D O I：

10.1002/aoc.4052

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Catalytic one-pot condensation of benzil, aldehyde and ammonium acetate have been successfully carried out using 2-hydroxyethylammonium formate (HEAF) grafted on a magnetic nanoparticles as a new heterogeneous catalyst. The as-prepared catalyst was characterized by FT-IR, TEM, FESEM, VSM, TGA and XRD. This catalyst indicated significant advantages, such as excellent yields, shorter reaction time, reusability of the catalyst and easy workup process.

引用

页数：8

共 50 条

[1] On the properties and structure of 2-hydroxyethylammonium formate ionic liquid
Hosseini, S. M.
Alavianmehr, M. M.
Gutierrez, A.
Khalifeh, R.
Moghadasi, J.
Aparicio, S.
[J]. JOURNAL OF MOLECULAR LIQUIDS, 2018, 249 : 233 - 244
[2] Magnetic nanoparticle supported ionic liquid as novel and effective heterogeneous catalyst for synthesis of substituted imidazoles under ultrasonic irradiation
Safari, Javad
Zarnegar, Zohre
[J]. MONATSHEFTE FUR CHEMIE, 2013, 144 (09): : 1389 - 1396
[3] Magnetic nanoparticle supported ionic liquid as novel and effective heterogeneous catalyst for synthesis of substituted imidazoles under ultrasonic irradiation
Javad Safari
Zohre Zarnegar
[J]. Monatshefte für Chemie - Chemical Monthly, 2013, 144 : 1389 - 1396
[4] Experimental and theoretical study of 2-hydroxyethylammonium formate ionic liquid plus alcohol mixtures
Alavianmehr, M. M.
Afshar, S.
Aparicio, S.
Haghani, A. H.
Hosseini, S. M.
Khalifeh, R.
[J]. JOURNAL OF MOLECULAR LIQUIDS, 2019, 281 : 269 - 279
[5] Domino Knoevenagel condensation, Michael addition, and cyclization using ionic liquid, 2-hydroxyethylammonium formate, as a recoverable catalyst
Shaterian, H. R.
Arman, M.
Rigi, F.
[J]. JOURNAL OF MOLECULAR LIQUIDS, 2011, 158 (02) : 145 - 150
[6] Synthesis of 2-amino-4H-chromenes and spirochromenes using basic ionic liquid, 2-hydroxyethylammonium formate as green, stable, and reusable catalyst
Tazeh, Kazem Sanchooli
Heydari, Reza
Fatahpour, Maryam
[J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2022, 69 (09) : 1680 - 1687
[7] 2-Hydroxyethylammonium Bisulfate (2-HEAS) as a Bronsted Acidic Ionic Liquid Catalyst for Esterification
Shahbazi, Mohammadjavad
Tavakoli, Akram
Hosseini, Mehdi
Khanian, Mitra
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2022, 61 (23) : 7874 - 7880
[8] 2-Hydroxyethylammonium Bisulfate (2-HEAS) as a Brønsted Acidic Ionic Liquid Catalyst for Esterification
Shahbazi, Mohammadjavad
Tavakoli, Akram
Hosseini, Mehdi
Khanian, Mitra
[J]. Industrial and Engineering Chemistry Research, 2022, 61 (23): : 7874 - 7880
[9] DFT and ab initio molecular dynamics simulation study of the infrared spectrum of the protic ionic liquid 2-hydroxyethylammonium formate
Paschoal, Vitor Hugo
Ribeiro, Mauro C. C.
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 25 (39) : 26475 - 26485
[10] Ambiphilic Dual Activation Role of a Task-Specific Ionic Liquid: 2-Hydroxyethylammonium Formate as a Recyclable Promoter and Medium for the Green Synthesis of β-Nitrostyrenes
Alizadeh, Abdolhamid
Khodaei, Mohammad M.
Eshghi, Ali
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (23): : 8295 - 8298

← 1 2 3 4 5 →