Core-shell nanostructure electrodes for improved electrocatalytic properties in methanol electrooxidation

被引：5

作者：

Lee, Jong-Min ^{[1
]}

Kim, Seong-Bae ^{[1
]}

Lee, Young-Woo ^{[1
]}

Kim, Do-Young ^{[1
]}

Han, Sang-Beom ^{[1
]}

Roh, Bumwook ^{[2
]}

Hwang, Inchul ^{[2
]}

Park, Kyung-Won ^{[1
]}

机构：

[1] Soongsil Univ, Dept Chem Engn, Seoul 156743, South Korea

[2] Hyundai Motor Co, Mabuk Ri, Gyeonggi Do, South Korea

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2012年 / 111卷

关键词：

Core-shell; TiN@C; Nanostructure; Support; Methanol electrooxidation; CARBON NANOTUBES; CATALYSTS; DEPOSITION; OXIDATION; SUPPORT; RU; NANOCOMPOSITE; NANOPARTICLES; FABRICATION; BEHAVIOR;

D O I：

10.1016/j.apcatb.2011.09.036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

TiN@C nanostructure supports consist of TiN as a core prepared at 900 degrees C in NH3 and carbon as a shell by heat treatment of the TiN at 900 degrees C in CH4 for 1, 3, and 6 h (referred as TiN@C-1 h, TiN@C-3 h, and TiN@C-6 h). The thickness of the carbon shell layers in the TiN@C supports increase with increasing reaction time at 900 degrees C in CH4. In particular, the TiN@C-1 h supported Pt catalyst exhibits much improved electrocatalytic properties toward methanol electrooxidation as compared to Pt catalysts on Vulcan XC-72R. (C) 2011 Elsevier BM. All rights reserved.

引用

页码：200 / 207

页数：8

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