Raman Spectra Study of K0.5Na0.5NbO3 Ferroelectric Thin Films

被引:45
|
作者
Ahn, Chang Won [1 ]
Hwang, Hak-In [1 ]
Lee, Kwang Sei [2 ]
Jin, Byung Moon [3 ]
Park, Sungmin [4 ]
Park, Gwangseo [4 ]
Yoon, Doohee [4 ]
Cheong, Hyeonsik [4 ]
Lee, Hai Joon [5 ]
Kim, Ill Won [5 ]
机构
[1] KETI, Convergence Components R&D Div, Songnam 463816, South Korea
[2] Inje Univ, Sch Comp Aided Sci, Kimhae 621749, South Korea
[3] Dong Eui Univ, Dept Phys, Pusan 614714, South Korea
[4] Sokang Univ, Dept Phys, Seoul 100611, South Korea
[5] Univ Ulsan, Dept Phys, Ulsan 680749, South Korea
关键词
NIOBATES;
D O I
10.1143/JJAP.49.095801
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have fabricated K0.5Na0.5NbO3 (KNN) thin films on Pt substrates by a chemical solution deposition method and investigated the effect of K and Na excess (0-30 mol %) for KNN thin film. The KNN film with 20 mol% excess K and Na was an optimized KNN perovskite phase. From the Raman spectra, a change in the scattering mode was observed due to the chemical composition fluctuations of the excess K and Na. The peak of the (v(1) + v(5)) internal vibrational mode in the NbO6 octahedra was split into two vibration modes which were shifted toward lower or higher wavenumbers depending on the K and Na cation deficiencies or redundancies. (C) 2010 The Japan Society of Applied Physics
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页数:4
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