Catalytic cyclopropanation and aziridination of alkenes by a Cu(I) complex of ferrocenyldiimine

被引：0
|
作者：
Cho, DJ [1 ]
Jeon, SJ [1 ]
Kim, HS [1 ]
Kim, TJ [1 ]
机构：
[1] Kyungpook Natl Univ, Dept Ind Chem, Taegu 702701, South Korea
来源：
SYNLETT | 1998年 / 06期
关键词：
cyclopropanation; aziridination; ferrocenyldiimine; copper(I) catalysis;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The copper(I) complex (FcNN)Cu(OTf) (1; FcNN = N,N'-ethylenebis[(ferrocenylmethylene)amine] catalyzes reactions of ethyl diazoacetate with alkenes to form cyclopropanes in high yield. The same complex also catalyzes nitrene transfer from PhI=NTs to alkenes to produce aziridines in high yield.
引用
收藏
页码：617 / +
页数：3
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