Synthesis, liquid crystalline behaviour and structure-property relationships of 1,3-bis(5-substituted-1,3,4-oxadiazol-2-yl)benzenes

被引:1
|
作者
Mabrouki, Afef [1 ]
Fouzai, Malek [2 ]
Soldera, Armand [3 ]
Kriaa, Abdelkader [1 ]
Hedhli, Ahmed [1 ]
机构
[1] Natl Higher Engn Sch Tunis, Lab Mol Organ Chem, 5 Ave Taha Hussein, Tunis 1089, Tunisia
[2] Univ Tunis El Manar, LR99ES16 Phys Lab Soft Matter & Electromagnet Mod, Tunis 2092, Tunisia
[3] Univ Sherbrooke, Quebec Ctr Funct Mat, Dept Chem, Sherbrooke, PQ J1K 2R1, Canada
来源
关键词
dipole moment; fluorine; liquid crystal; oxadiazole; SEMIFLUORINATED NORMAL-ALKANES; PHASES; TRANSITIONS; 1,3,4-OXADIAZOLES; BENZENE; SYSTEMS; DESIGN; CHAINS; UNITS;
D O I
10.3762/bjoc.16.17
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Two series containing 1,3-bis(1,3,4-oxadiazol-2-yl)benzene as a rigid core (RC) and alkyl or perfluoroalkyl as terminal chains were synthesized and characterized. Liquid crystal properties of the synthesized compounds have been investigated by polarizing optical microscopy, differential scanning calorimetry and X-ray diffraction techniques. Conformation effects of the synthesized products on the dipole moments were also investigated.
引用
收藏
页码:149 / 158
页数:10
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