The specifics of carbon dioxide hydrogenation to formic acid in the presence of triphenylphosphine rhodium complexes

被引：0

作者：

Ezhova, NN ^{[1
]}

Kolesnichenko, NV ^{[1
]}

Bulygin, AV ^{[1
]}

Kremleva, EV ^{[1
]}

Filatova, MP ^{[1
]}

Slivinskii, EV ^{[1
]}

机构：

[1] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow 117912, Russia

来源：

PETROLEUM CHEMISTRY | 2004年 / 44卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Results on CO2 hydrogenation to formic acid in the presence of RhCl(PPh3)(3) and HRh(PPh3)(4) complexes at room temperature and a pressure of 6.0 MPa (CO2 : H-2 = 2) are presented. Certain features of the reaction in the presence of these complexes are compared. On the basis of kinetic data and P-31 NMR measurements, it was shown that catalyst deactivation is mainly due to the elimination of PPh3. A method for stabilizing the catalyst by introducing inorganic salts into the reaction solution was proposed. The new effective catalyst system including, RhCl(PPh3)(3), PPh3, and KNO3 makes it possible to hydrogenate CO2 in 100% yield.

引用

页码：24 / 27

页数：4

共 50 条

[1] Carbon dioxide hydrogenation to formic acid in the presence of rhodium-oligoarylphosphonite catalyst systems
N. V. Kolesnichenko
E. V. Kremleva
A. T. Teleshov
N. N. Ezhova
D. A. Ganin
Van Te
E. V. Slivinskii
[J]. Petroleum Chemistry, 2006, 46 : 22 - 24
[2] Carbon dioxide hydrogenation to formic acid in the presence of rhodium-oligoarylphosphonite catalyst systems
Kolesnichenko, N. V.
Kremleva, E. V.
Teleshov, A. T.
Ezhova, N. N.
Ganin, D. A.
Te, Van
Slivinskii, E. V.
[J]. PETROLEUM CHEMISTRY, 2006, 46 (01) : 22 - 24
[3] RHODIUM-CATALYZED HYDROGENATION OF CARBON-DIOXIDE TO FORMIC-ACID
TSAI, JC
NICHOLAS, KM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) : 5117 - 5124
[4] Hydrogenation of carbon dioxide in the presence of rhodium catalysts
Kolesnichenko, NV
Ezhova, NN
Kremleva, EV
Slivinskii, EV
[J]. RUSSIAN CHEMICAL BULLETIN, 2004, 53 (11) : 2542 - 2545
[5] Hydrogenation of carbon dioxide in the presence of rhodium catalysts
N. V. Kolesnichenko
N. N. Ezhova
E. V. Kremleva
E. V. Slivinskii
[J]. Russian Chemical Bulletin, 2004, 53 : 2542 - 2545
[6] Hydrogenation of carbondioxide to form formic acid, methanol, methylformate in the presence of rhodium complexes.
Han, SH
Ejova, NN
Kolesnichenko, NV
Uhm, SJ
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 214 : 42 - PETR
[7] Kinetic Studies on the Hydrogenation of Carbon Dioxide to Formic Acid using a Rhodium Complex as Catalyst
Dietrich, Jens
Schindler, Siegfried
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (14): : 2487 - 2494
[8] Catalytic Hydrogenation of Carbon Dioxide to Formic Acid
Behr, Arno
Nowakowski, Kristina
[J]. CO2 CHEMISTRY, 2014, 66 : 223 - 258
[9] HYDROGENATION OF DIENES IN PRESENCE OF RHODIUM COMPLEXES WITH TRIPHENYLPHOSPHINE AND DIMETHYL-SULFOXIDE
FREIDLIN, LK
KOPYTTSE.YA
LITVIN, EF
NAZAROVA, NM
[J]. ZHURNAL ORGANICHESKOI KHIMII, 1974, 10 (03): : 430 - 432
[10] ACTIVATION OF CARBON-DIOXIDE .4. RHODIUM-CATALYZES HYDROGENATION OF CARBON-DIOXIDE TO FORMIC-ACID
LEITNER, W
DINJUS, E
GASSNER, F
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 475 (1-2) : 257 - 266

← 1 2 3 4 5 →