Three New Oleanane-Type Triterpene Saponins from Gladiolus gandavensis

被引：5
|
作者：
Tai, Zhi-Gang [1 ]
Cai, Le [1 ]
Yang, Ya-Bin [1 ]
Liu, Chuan-Shui [1 ]
Xia, Jian-Jun [1 ,2 ]
Ding, Zhong-Tao [1 ]
机构：
[1] Yunnan Univ, Key Lab Med Chem Nat Resource, Minist Educ, Sch Chem Sci & Technol, Kunming 650091, Peoples R China
[2] Hongyun Honghe Tobacco Grp Co Ltd, Ctr Technol, Kunming 650202, Peoples R China
来源：
BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2010年 / 31卷 / 10期
关键词：
Gladiolus gandavensis; Triterpene saponins; ANTHRAQUINONES; GLYCOSIDES;
D O I：
10.5012/bkcs.2010.31.10.2786
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three new oleanane-type triterpene saponins (1, 2 and 3) were isolated from aerial parts of Gladiolus gandavensis, along with two known compounds (4 and 5). Their structures were elucidated as 29-O-(beta-D-glucopyranosyl)-2 beta,3 beta-dihydroxyolean-12-en-28-oicacid(1), 3-O-(beta-D-xylopyranosyl)-29-O-(beta-D-glucopyranosyl)-12-en-28-oic acid (2), and 2 beta,3 beta,29-trihydroxyolean-12-en-28-oic acid 28-O-[beta-D-glucopyranosyl(1 -> 2)-(alpha-L-rhamnopyranosyl(1 -> 6))-beta-D-glucopyranosyl] ester (3), by spectroscopic methods, and by comparison with known analogues. These oleanane-type triterpene saponins glycosidated at C-29 were not obtained frequently.
引用
收藏
页码：2786 / 2790
页数：5
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