Five-fold interpenetrating diamondlike 3D metal-organic frameworks constructed from the rigid 1,2-di(pyridin-4-yl)ethane-1,2-diol ligand and aromatic carboxylate

被引:17
|
作者
Wei, Yong-Li [1 ]
Li, Jia-Bin [1 ]
Song, Wen-Chao [1 ]
Zang, Shuang-Quan [1 ]
机构
[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450001, Peoples R China
基金
中国国家自然科学基金;
关键词
Coordination polymer; Diamondoid structure; Five-fold interpenetration; Luminescent properties; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; NETWORKS; CHAINS; ARCHITECTURES; COMPLEXES; SORPTION; TOPOLOGY; CENTERS;
D O I
10.1016/j.inoche.2011.09.028
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two novel five-fold interpenetrating diamondlike 3D coordination polymers, namely [M(bpg)(bdc) 2H(2)O] (M=Zn(II), Cd(II)) have been synthesized by the hydrothermal reactions between M(NO3)(2) 6H(2)O(M=Zn (II), Cd(II)), meso-alpha,beta-bi(4-pyridyl) glycol (bpg) and 1,4-benzenedicarboxylic acid (H(2)bdc). The two compounds were characterized by X-ray single crystal diffraction, infrared spectroscopy, elemental analysis, thermogravimetric analysis, and their fluorescence properties were also investigated. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:16 / 20
页数:5
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