Single-step co-deposition of nanostructured tungsten oxide supported gold nanoparticles using a gold-phosphine cluster complex as the gold precursor

被引:5
|
作者
Molkenova, Anara [1 ,4 ]
Sarip, Rozie [1 ]
Sathasivam, Sanjay [1 ]
Umek, Polona [2 ]
Vallejos, Stella [2 ,5 ]
Blackman, Chris [1 ,3 ]
Hogarth, Graeme [1 ,6 ]
Sankar, Gopinathan [1 ]
机构
[1] Univ London Univ Coll, Dept Chem, London WC1H 0AJ, England
[2] Jozef Stefan Inst, Dept Solid State Phys, Ljubljana, Slovenia
[3] London Ctr Nanotechnol, London WC1H 0AH, England
[4] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Chem Engn, Tokyo, Japan
[5] Brno Univ Technol, Fac Elect Engn & Commun, SIX Res Ctr, CZ-61600 Brno, Czech Republic
[6] Kings Coll London, Dept Chem, London SE1 1DB, England
关键词
CVD; nanoparticle; catalyst; CHEMICAL-VAPOR-DEPOSITION; WO3; NANONEEDLES; AU; OXIDATION; CATALYSTS; EPOXIDATION; CVD;
D O I
10.1088/1468-6996/15/6/065004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The use of a molecular gold organometallic cluster in chemical vapour deposition is reported, and it is utilized, together with a tungsten oxide precursor, for the single-step co-deposition of (nanostructured) tungsten oxide supported gold nanoparticles (NPs). The deposited gold-NP and tungsten oxide supported gold-NP are highly active catalysts for benzyl alcohol oxidation; both show higher activity than SiO2 supported gold-NP synthesized via a solution-phase method, and tungsten oxide supported gold-NP show excellent selectivity for conversion to benzaldehyde.
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页数:7
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