Molecular compounds exhibiting coupled conducting and magnetic properties and based on (cation)(n)[M(dmit)](2) and (BETS)(2)(anion) salts

被引：10

作者：

Kushch, N

Faulmann, C

Cassoux, P

Valade, L

Malfant, I

Legros, JP

Bowlas, C

Errami, A

Kobayashi, A

Kobayashi, H

机构：

[1] CNRS,LCC,F-31077 TOULOUSE,FRANCE

[2] UNIV TOULOUSE 3,F-31077 TOULOUSE,FRANCE

[3] UNIV TOKYO,FAC SCI,DEPT CHEM,BUNKYO KU,TOKYO 113,JAPAN

[4] INST MOLEC SCI,OKAZAKI,AICHI 444,JAPAN

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1996年 / 284卷

关键词：

D O I：

10.1080/10587259608037927

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A systematic study has been carried out on a range of metal complexes of the type (cation)(n)[M(dmit)(2)] (cation = NH(y)R(4-y); y = 1 or 2; n = x, 1, 2; R = ethyl, propyl or butyl, or cation = organic radical cations containing one or two TTF moieties; M = Ni or Pd and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolato). The synthesis of these complexes, the crystal structure of (NHBu(3))(2)[Ni(dmit)(2)] and neutral [Ni(dmit)(2)], their solution redox behaviour and the solid state conductivities of the non-integer oxidation state compounds obtained by electrocrystallization techniques are presented. Synthesis, structure and properties of new compounds of the family of (BETS)(2)(anion) compounds with (CuxCly)(n-) and[(FeCl4)(1-x)(GaCl4)(x)](-) anions are described.

引用

页码：247 / 258

页数：12

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