Solvent Effect on Electrochemical Properties of a Co(II)-Based Metallo-Supramolecular Polymer Film

被引：4
|
作者：
Hsu, Chih-Yu [1 ]
Zhang, Jian [1 ,2 ]
Moriyama, Satoshi [2 ,3 ]
Higuchi, Masayoshi [1 ,3 ]
机构：
[1] Natl Inst Mat Sci, Polymer Mat Unit, Elect Funct Mat Grp, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
[2] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton MANA, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
[3] JST CREST, Kawaguchi, Saitama, Japan
来源：
MACROMOLECULAR SYMPOSIA | 2016年 / 363卷 / 01期
关键词：
bisterpyridine; cobalt; electrochemistry; metallo-supramolecular polymer; solvent effect; ELECTROCHROMIC PROPERTIES; COMPLEXES; TERPYRIDINE; COBALT; CHEMISTRY; IONS; ELECTRODE; EXCHANGE; LIGANDS;
D O I：
10.1002/masy.201500136
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The influence of solvents on the electrochemical properties of a Co(II)-bisterpyridine-based metallo-supramolecular polymer (polyCo) thin films are studied. A redox couple of the polyCo film on GC electrode is observed in the reduction domain due to the redox reaction between Co(II) and Co(I) which belongs to a Nernstian reversible process in aqueous electrolyte solution. While a significant difference on the electrochemical stability of polyCo film is found in the electrolyte solution of organic solvent. A shrinking behaviour of the film is observed after redox switching in acetonitrile solution. The formation of the mixed-ligand of cobalt ion with water molecules as well as the hydrophilic property of the anion enable a stable redox switching of polyCo film in aqueous electrolytes.
引用
收藏
页码：12 / 19
页数：8
相关论文
共 50 条
  • [1] A Co(II)-based metallo-supramolecular polymer as a novel enzyme immobilization matrix for electrochemical glucose biosensing
    Hsu, Chih-Yu
    Sato, Takashi
    Moriyama, Satoshi
    Higuchi, Masayoshi
    [J]. EUROPEAN POLYMER JOURNAL, 2016, 83 : 499 - 506
  • [2] Fe(II)-Based Metallo-Supramolecular Polymer Film for Electrochemical Detection of Nitrite: Studies of Kinetics and Reaction Mechanisms
    Awal, Abdul
    Mia, Md. Mithu
    Sarkar, Shifa
    Islam, Santa
    Sarker, Sohag
    Nayem, S. M. Abu
    Hossain, Md. Delwar
    Ahammad, A. J. Saleh
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2023, 170 (03)
  • [3] Zn(II)-containing metallo-supramolecular polymers: synthesis, photophysical and electrochemical properties
    Liu, Lin
    Hu, Zhiwei
    Wu, Chunlin
    Chen, Xuegang
    Luo, Xianyi
    Li, Jie
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2019, 56 (10): : 918 - 925
  • [4] Effect of solvent quality on the properties of multi-responsive metallo-supramolecular gels
    Weng, Wengui
    Jamieson, Alex M.
    Rowan, Stuart
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233
  • [5] A vapoluminescent Eu-based metallo-supramolecular polymer
    Sato, Takashi
    Higuchi, Masayoshi
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (41) : 4947 - 4949
  • [6] Electrochromic Os(II)-Based Metallo-Supramolecular Polymers
    Bera, Manas Kumar
    Chakraborty, Chanchal
    Rana, Utpal
    Higuchi, Masayoshi
    [J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2018, 39 (22)
  • [7] Precise Synthesis of Alternate Fe(II)/Os(II)-Based Bimetallic Metallo-Supramolecular Polymer
    Bera, Manas K.
    Ninomiya, Yoshikazu
    Yoshida, Takefumi
    Higuchi, Masayoshi
    [J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2020, 41 (01)
  • [8] Thermally stable electrochromic devices using Fe(II)-based metallo-supramolecular polymer
    Mondal, Sanjoy
    Yoshida, Takefumi
    Rana, Utpal
    Bera, Manas Kumar
    Higuchi, Masayoshi
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2019, 200
  • [9] Multifunctional Pt(II)-Based Metallo-Supramolecular Polymer with Carboxylic Acid Groups: Electrochemical, Mechanochemical, Humidity, and pH Response
    Chakraborty, Chanchal
    Rana, Utpal
    Moriyama, Satoshi
    Higuchi, Masayoshi
    [J]. ACS APPLIED POLYMER MATERIALS, 2020, 2 (09) : 4149 - 4159
  • [10] Platinum(II)-Based Metallo-Supramolecular Polymer with Controlled Unidirectional Dipoles for Tunable Rectification
    Chakraborty, Chanchal
    Pandey, Rakesh K.
    Hossain, Md. Delwar
    Futera, Zdenek
    Moriyama, Satoshi
    Higuchi, Masayoshi
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (34) : 19034 - 19042
12345